Zahlenwerte und Funktionen aus Naturwissenschaften und Technik Von Landolt-Bornstein. Neue Serie. Gesamtherausgabe: K. H. Hellwege. Gruppe II: Atom- und Molekularphysik. Band 1: Magnetische Eigenschaften freier Radikale. Von H. Fischer. Herausgeber: K. H. Hellwege und A. M. Hellwege. Pp. x + 154. (Berlin: Springer-Verlag, 1965.) 68 D.M.

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Electron Spin Resonance

We report synthesis and superconductivity at 3.7 K in PrO0.5F0.5BiS2. The newly discovered material belongs to the layered sulfide based REO0.5F0.5BiS2 compounds having a ZrCuSiAs-type structure. The bulk polycrystalline compound is synthesized by the vacuum encapsulation technique at 780 ∘C in a single step. Detailed structural analysis has shown that the as synthesized PrO0.5F0.5BiS2 is crystallized in a tetragonal P4/nmm space group with lattice parameters a=4.015(5) A, c=13.362(4) A. Bulk superconductivity is observed in PrO0.5F0.5BiS2 below 4 K from magnetic and transport measurements. Electrical transport measurements showed superconducting transition temperature (Tc) onset at 3.7 K and Tc(ρ=0) at 3.1 K. The hump at Tc related to the superconducting transition is not observed in the heat capacity measurement and rather a Schottky-type anomaly is observed at below ∼6 K. The compound is slightly semiconducting in a normal state. Isothermal magnetization (MH) exhibited typical type II behavior with a lower critical field (Hc1) of around 8 Oe.

Synthesis and Superconductivity of New BiS2 Based Superconductor PrO0.5F0.5BiS2

We study the pairing symmetry of a two-orbital J1-J2 model for FeAs layers in oxypnictides. We show that the mixture of an intraorbital unconventional s_{x;{2}y;{2}} approximately cos(k_{x})cos(k_{y}) pairing symmetry, which changes sign between the electron and hole Fermi surfaces, and a very small d_{x;{2}-y;{2}} approximately cos(k_{x})-cos(k_{y}) component is favored in a large part of the J1-J2 phase diagram. A pure s_{x;{2}y;{2}} pairing state is favored for J2>J1. The signs of the d_{x;{2}-y;{2}} order parameters in the two different orbitals are opposite. While a small d_{xy} approximately sin(k_{x})sin(k_{y}) interorbital pairing coexists in the above phases, the intraorbital d_{xy} pairing is not favored even for large J2.

http://absimage.aps.org/image/MAR09/MWS_MAR09-2008-001927.pdf

Pairing Symmetry in a Two-Orbital Exchange Coupling Model of Oxypnictides

A very recent report on the observation of superconductivity in Bi(4)O(4)S(3) [Mizuguchi, Y.; http://arxiv.org/abs/1207.3145] could potentially reignite the search for superconductivity in a broad range of layered sulfides. We report here the synthesis of Bi(4)O(4)S(3) at 500 °C by a vacuum encapsulation technique and its basic characterizations. The as-synthesized Bi(4)O(4)S(3) was contaminated with small amounts of Bi(2)S(3) and Bi impurities. The majority phase was found to be tetragonal (space group I4/mmm) with lattice parameters a = 3.9697(2) A and c = 41.3520(1) A. Both AC and DC magnetization measurements confirmed that Bi(4)O(4)S(3) is a bulk superconductor with a superconducting transition temperature (T(c)) of 4.4 K. Isothermal magnetization (M-H) measurements indicated closed loops with clear signatures of flux pinning and irreversible behavior. The lower critical field (H(c1)) at 2 K for the new superconductor was found to be ~15 Oe. Magnetotransport measurements showed a broadening of the resistivity (ρ) and a decrease in T(c) (ρ = 0) with increasing magnetic field. The extrapolated upper critical field H(c2)(0) was ~31 kOe with a corresponding Ginzburg-Landau coherence length of ~100 A . In the normal state, the ρ ~ T(2) dependence was not indicated. Hall resistivity data showed a nonlinear magnetic field dependence. Our magnetization and electrical transport measurements substantiate the appearance of bulk superconductivity in as-synthesized Bi(4)O(4)S(3). On the other hand, Bi heat-treated at the same temperature is not superconducting, thus excluding the possibility of impurity-driven superconductivity in the newly discovered superconductor Bi(4)O(4)S(3).

Bulk superconductivity in bismuth oxysulfide Bi4O4S3.

We report a strategy to induce superconductivity in the BiS$_2$-based compound LaOBiS$_2$ Instead of substituting F for O, we increase the charge-carrier density (electron dope) via substitution of tetravalent Th$^{+4}$, Hf$^{+4}$, Zr$^{+4}$, and Ti$^{+4}$ for trivalent La$^{+3}$ It is found that both the LaOBiS$_2$ and ThOBiS$_2$ parent compounds are bad metals and that superconductivity is induced by electron doping with \emph{T$_c$} values of up to 285 K The superconducting and normal states were characterized by electrical resistivity, magnetic susceptibility, and heat capacity measurements We also demonstrate that reducing the charge-carrier density (hole doping) via substitution of divalent Sr$^{+2}$ for La$^{+3}$ does not induce superconductivity

Superconductivity induced by electron doping in the system La1-xMxOBiS2 (M = Ti, Zr, Hf, Th)

Bulk polycrystalline samples, SmFeAsO and the iso-structural superconducting SmFeAsO0.80F0.20 are explored through resistivity with temperature under magnetic field {\rho}(T, H), AC and DC magnetization (M-T), and Specific heat (Cp) measurements. The Resistivity measurement shows superconductivity for x = 0.20 sample with Tc(onset) ~ 51.7K. The upper critical field, [Hc2(0)] is estimated ~3770kOe by Ginzburg-Landau (GL) theory. Broadening of superconducting transition in magneto transport is studied through thermally activated flux flow in applied field up to 130 kOe. The flux flow activation energy (U/kB) is estimated ~1215K for 1kOe field. Magnetic measurements exhibited bulk superconductivity with lower critical field (Hc1) of ~1.2kOe at 2K. In normal state, the paramagnetic nature of compound confirms no trace of magnetic impurity which orders ferromagnetically. AC susceptibility measurements have been carried out for SmFeAsO0.80F0.20 sample at various amplitude and frequencies of applied AC drive field. The inter-granular critical current density (Jc) is estimated. Specific heat [Cp(T)] measurement showed an anomaly at around 140K due to the SDW ordering of Fe, followed by another peak at 5K corresponding to the antiferromagnetic (AFM) ordering of Sm+3 ions in SmFeAsO compound. Interestingly the change in entropy (marked by the Cp transition height) at 5K for Sm+3 AFM ordering is heavily reduced in case of superconducting SmFeAsO0.80F0.20 sample.

Magneto-transport and magnetic susceptibility of SmFeAsO1-xFx (x = 0.0 and 0.20)

We present the complex harmonic magnetic susceptibilities of the FeSeTe polycrystalline superconducting sample. The ac magnetic susceptibility is measured as a function of various external perturbations such as temperature, the AC magnetic field amplitude, frequency, and the magnitude of DC bias field. The in phase and out of phase components of the fundamental and third harmonics of ac susceptibility are found to vary as a function of the AC drive field. The imaginary part of third harmonics shows two peaks as a function of frequency, one negative in magnitude and another is positive. The negative peak shifts towards the lower temperature and positive peak is shifted towards the higher temperature as we increase the frequency. To better understand the AC magnetic response under the influence of various perturbations, we have analyzed the polar plot of the complex ac susceptibility for both the harmonics. Our analysis suggests that the studied sample is in vortex glass state, characterized by a collective flux creep state within Beans model and the Kim Anderson model is ruled out.

Investigation of fundamental and higher harmonic AC magnetic susceptibility of FeSe0.5Te0.5 Superconductor.

In this paper, we demonstrate a vanadium dioxide (VO2) based absorption modulator on silicon-on-insulator platform. The optical modulation is achieved by thermally tuning (local) the refractive index (phase) of VO2. We use a micro-ring resonator for optical modulation in our experiment. The device shows a low insertion loss of 1.48 dB and high extinction ratio change of 16 dB. The transition spectrum analysis yields an approximately 1.2 change in refractive index across the transition. Mach-Zehnder configuration is used to analyze the switching performance of the device.

Anand Pal

Papers

Magneto-transport and magnetic susceptibility of SmFeAsO1-xFx (x = 0.0 and 0.20)

Investigation of fundamental and higher harmonic AC magnetic susceptibility of FeSe0.5Te0.5 Superconductor.

Refractive index tunability and switching with vanadium dioxide on silicon waveguides