Understanding the complementary roles of surface energy and roughness on natural nonwetting surfaces has led to the development of a number of biomimetic superhydrophobic surfaces, which exhibit apparent contact angles with water greater than 150 degrees and low contact angle hysteresis. However, superoleophobic surfaces-those that display contact angles greater than 150 degrees with organic liquids having appreciably lower surface tensions than that of water-are extremely rare. Calculations suggest that creating such a surface would require a surface energy lower than that of any known material. We show how a third factor, re-entrant surface curvature, in conjunction with chemical composition and roughened texture, can be used to design surfaces that display extreme resistance to wetting from a number of liquids with low surface tension, including alkanes such as decane and octane.

http://science.sciencemag.org/content/sci/318/5856/1618.full.pdf

Designing Superoleophobic Surfaces

Some of the greatest scientists including Poisson, Faraday, Maxwell, Rayleigh, and Einstein have contributed to the theory of composite materials Mathematically, it is the study of partial differential equations with rapid oscillations in their coefficients Although extensively studied for more than a hundred years, an explosion of ideas in the last five decades (and particularly in the last three decades) has dramatically increased our understanding of the relationship between the properties of the constituent materials, the underlying microstructure of a composite, and the overall effective (electrical, thermal, elastic) moduli which govern the macroscopic behavior This renaissance has been fueled by the technological need for improving our knowledge base of composites, by the advance of the underlying mathematical theory of homogenization, by the discovery of new variational principles, by the recognition of how important the subject is to solving structural optimization problems, and by the realization of the connection with the mathematical problem of quasiconvexification This 2002 book surveys these exciting developments at the frontier of mathematics

/pdf/the-theory-of-composites-1ruy3p9ier.pdf

The Theory of Composites

We discuss in this review how the roughness of a solid impacts its wettability. We see in particular that both the apparent contact angle and the contact angle hysteresis can be dramatically affected by the presence of roughness. Owing to the development of refined methods for setting very well-controlled micro- or nanotextures on a solid, these effects are being exploited to induce novel wetting properties, such as spontaneous filmification, superhydrophobicity, superoleophobicity, and interfacial slip, that could not be achieved without roughness.

Wetting and Roughness

In the 19th century, Oscar Wilde stated “We live, I regret to say, in an age of surfaces”. Today, we do so even more, and we do not regret it: key advances in the understanding and fabrication of surfaces with controlled wetting properties are about to make the dream of a contamination-free (or 'no-clean') surface come true. Two routes to self-cleaning are emerging, which work by the removal of dirt by either film or droplet flow. Although a detailed understanding of the mechanisms underlying the behaviour of liquids on such surfaces is still a basic research topic, the first commercial products in the household-commodity sector and for applications in biotechnology are coming within reach of the marketplace. This progress report describes the current status of understanding of the underlying mechanisms, the concepts for making such surfaces, and some of their first applications.

Self-cleaning surfaces - virtual realities

Biological materials: Structure and mechanical properties

This insect has a tailor-made covering for collecting water from early-morning fog. Some beetles in the Namib Desert collect drinking water from fog-laden wind on their backs1. We show here that these large droplets form by virtue of the insect's bumpy surface, which consists of alternating hydrophobic, wax-coated and hydrophilic, non-waxy regions. The design of this fog-collecting structure can be reproduced cheaply on a commercial scale and may find application in water-trapping tent and building coverings, for example, or in water condensers and engines.

Water capture by a desert beetle

Biomimetics is the extraction of good design from nature. One approach to optical biomimetics focuses on the use of conventional engineering methods to make direct analogues of the reflectors and anti-reflectors found in nature. However, recent collaborations between biologists, physicists, engineers, chemists and materials scientists have ventured beyond experiments that merely mimic what happens in nature, leading to a thriving new area of research involving biomimetics through cell culture. In this new approach, the nanoengineering efficiency of living cells is harnessed and natural organisms such as diatoms and viruses are used to make nanostructures that could have commercial applications.

Biomimetics of photonic nanostructures

Structures that cause colour or provide antireflection have been found in both living and extinct animals in a diversity of forms, including mirror-reflective and diffractive devices. An overview of this diversity is presented here, and behavioural and evolutionary implications are introduced.

https://iopscience.iop.org/article/10.1088/1464-4258/2/6/201/pdf

515 million years of structural colour

Beetles in dimly lit tropical forests often display structural colours1, but in direct sunlight only part of the insect can be seen from any direction — it appears as a spot of light because multilayer reflectors on its rounded surface act like mirrors2,3. Here we describe a beetle, Pachyrhynchus argus, found in forests in northeastern Queensland, Australia, that has a metallic coloration that is visible from any direction owing to a photonic crystal structure analogous to that of opal4. To our knowledge, this is the first recorded example of an opal-type structure in an animal.

Structural colour: opal analogue discovered in a weevil.

The most intense colours displayed in nature result from either multilayer reflectors or linear diffraction gratings1,2,3 Here we investigate the spectacular iridescence of a spine (notoseta) from the sea mouse Aphrodita sp (Polychaeta: Aphroditidae) The spine normally appears to be deep red in colour, but when light is incident perpendicular to the axis of the spine, different colours are seen as stripes running parallel to the axis of the spine; over a range of smaller incident angles, the complete visible spectrum is reflected with a reflectivity of 100% to the human eye The simple structure responsible for this effect is a remarkable example of photonic engineering by a living organism

Andrew R. Parker

Papers

Water capture by a desert beetle

Biomimetics of photonic nanostructures

515 million years of structural colour

Structural colour: opal analogue discovered in a weevil.

Aphrodite's iridescence