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Andrey Yu. Chernenko
Publications - 10
Citations - 260
Andrey Yu. Chernenko is an academic researcher. The author has contributed to research in topics: Catalysis & Reductive elimination. The author has an hindex of 5, co-authored 7 publications receiving 182 citations.
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Journal ArticleDOI
A New Mode of Operation of Pd-NHC Systems Studied in a Catalytic Mizoroki–Heck Reaction
Alexander V. Astakhov,Oleg V. Khazipov,Andrey Yu. Chernenko,Dmitry V. Pasyukov,Alexey S. Kashin,Evgeniy G. Gordeev,Victor N. Khrustalev,Victor M. Chernyshev,Valentine P. Ananikov +8 more
TL;DR: In this paper, a detailed study involving 19 different Pd-NHC complexes with imidazolium, benzimidazolate, and triazolate ligands has been carried out and revealed a new mode of operation of metal NHC systems.
Journal ArticleDOI
Revealing the unusual role of bases in activation/deactivation of catalytic systems: O–NHC coupling in M/NHC catalysis
Victor M. Chernyshev,Oleg V. Khazipov,Maxim A. Shevchenko,Andrey Yu. Chernenko,Alexander V. Astakhov,Dmitry B. Eremin,Dmitry V. Pasyukov,Alexey S. Kashin,Valentine P. Ananikov +8 more
TL;DR: In this paper, the behavior of M(ii)/NHC (M = Pd, Pt, Ni) complexes in solution under the action of bases conventionally engaged in catalysis (KOH, NaOH, t-BuOK, Cs2CO3, K2 CO3, etc.).
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Fast and Slow Release of Catalytically Active Species in Metal/NHC Systems Induced by Aliphatic Amines
Oleg V. Khazipov,Maxim A. Shevchenko,Andrey Yu. Chernenko,Alexander V. Astakhov,Dmitry V. Pasyukov,Dmitry B. Eremin,Yan V. Zubavichus,Victor N. Khrustalev,Victor N. Khrustalev,Victor M. Chernyshev,Valentine P. Ananikov +10 more
TL;DR: The behavior of ubiquitously used nickel, palladium, and platinum complexes containing N-heterocyclic carbene ligands was studied in solution in the presence of aliphatic amines and Bis-NHC metal complexes M(NHC)2X2 were found to be significantly more stable and represented a molecular reservoir of catalytically active species.
Journal ArticleDOI
Diversity Oriented Synthesis of Polycyclic Heterocycles through the Condensation of 2-Amino[1,2,4]triazolo[1,5-a]pyrimidines with 1,3-Diketones.
Dmitry A. Pyatakov,A. N. Sokolov,Alexander V. Astakhov,Andrey Yu. Chernenko,Artem N. Fakhrutdinov,Victor B. Rybakov,Vladimir V. Chernyshev,Victor M. Chernyshev +7 more
TL;DR: The acid-catalyzed condensation between 2-aminosubstituted [1,2,4]triazolo[1,5-a]pyrimidines and their analogues with various saturation of the pyrimidine ring and 1,3-diketones or 1,1,3,3
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Preventing Pd–NHC bond cleavage and switching from nano-scale to molecular catalytic systems: amines and temperature as catalyst activators
Oleg V. Khazipov,Maxim A. Shevchenko,Dmitry V. Pasyukov,Andrey Yu. Chernenko,Alexander V. Astakhov,Victor A. Tafeenko,Victor M. Chernyshev,Valentine P. Ananikov,Valentine P. Ananikov +8 more
TL;DR: Insight is gained into conditions required for the efficient use of amines as activators of molecular Pd/NHC catalysis and preventing the undesirable reductive cleavage of the Pd–NHC bond in catalytic systems.