Coordination behaviour of sulfanilamide derivatives.

Synthesis, characterization and antibacterial activity of a tridentate Schiff base derived from cephalothin and sulfadiazine, and its transition metal complexes.

The reaction of H-SD (sulfadiazine) with Zn(OAc)2·2H2O in water–ethanol under solvothermal reaction conditions yields crystals of Zn(SD)2 (1) suitable for X-ray analysis and its 1-D polymeric nature is biologically relevant to the slow release of Zn2+ when applied in topical burn therapy.

Crystal structure of zinc(II) 2-sulfanilamidopyrimidine: a widely used topical burn drug

Syntheses and characterisation of mercury complexes of sulfadiazine, sulfamerazine and sulfamethazine

Silver(I) and copper(II) complexes of 4-amino-N-(4,6-dimethyl-2-pyrimidinyl) benzenesulfonamide (smz) have been synthesized and characterized by elemental analysis and infrared (IR), 1H NMR, and UV–vis spectroscopy. [Ag(smz)(pyridine)] (1) crystallizes in monoclinic system with space group P21/c and Z = 4, while [Cu(smz)2(pyridine)2]·H2O (2) crystallizes in triclinic system with space group P-1 and Z = 2. X-ray analysis revealed that silver in 1 is four-coordinate exhibiting distorted tetrahedral geometry, while copper in 2 is coordinated to six nitrogens leading to a highly distorted octahedral geometry. The molecular structures of both 1 and 2 are stabilized by N–H⋯O and C–H⋯π intermolecular and C–H⋯O intramolecular interactions. Water plays a significant role in crystal packing by forming strong N–H⋯Owater intramolecular as well as Owater–H⋯N intermolecular interactions in 2. The results of IR, UV–vis, 1H NMR spectral data and thermal analysis for 1 and 2 suggest that the binding of silver and copper t...

Synthesis, spectroscopic characterization, antimicrobial activity and crystal structure of silver and copper complexes of sulfamethazine

Metallation of 2-sulfanilamidopyrimidine (sulfadiazine). X-ray diffraction structure and solution behaviour of bis(sulfadiazinato) mercury(II) bis(dimethylsulfoxide)

Angel Garci´a-Raso

Papers

Metallation of 2-sulfanilamidopyrimidine (sulfadiazine). X-ray diffraction structure and solution behaviour of bis(sulfadiazinato) mercury(II) bis(dimethylsulfoxide)