Single-molecule surface-enhanced Raman scattering (SM-SERS) is one of the vital applications of plasmonic nanoparticles. The SM-SERS sensitivity critically depends on plasmonic hot-spots created at the vicinity of such nanoparticles. In conventional fluid-phase SM-SERS experiments, plasmonic hot-spots are facilitated by chemical aggregation of nanoparticles. Such aggregation is usually irreversible, and hence, nanoparticles cannot be re-dispersed in the fluid for further use. Here, we show how to combine SM-SERS with plasmon polariton-assisted, reversible assembly of plasmonic nanoparticles at an unstructured metal–fluid interface. One of the unique features of our method is that we use a single evanescent-wave optical excitation for nanoparticle assembly, manipulation and SM-SERS measurements. Furthermore, by utilizing dual excitation of plasmons at metal–fluid interface, we create interacting assemblies of metal nanoparticles, which may be further harnessed in dynamic lithography of dispersed nanostructures. Our work will have implications in realizing optically addressable, plasmofluidic, single-molecule detection platforms. Plasmonic hot-spot generation in solution is not reversible for single-molecule surface-enhanced Raman scattering, which limits its applications. Patra et al.tackle this problem by integrating this technique with thermo-plasmon-assisted reconfiguration of nanoparticles at a metal–fluid interface.

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Plasmofluidic single-molecule surface-enhanced Raman scattering from dynamic assembly of plasmonic nanoparticles

Conventional optical tweezers, formed at the diffraction-limited focus of a laser beam, have become a powerful and flexible tool for manipulating micrometre-sized objects. Extending optical trapping down to the nanometre scale would open unprecedented opportunities in many fields of science, where such nano-optical tweezers would allow the ultra-accurate positioning of single nano-objects. Among the possible strategies, the ability of metallic nanostructures to control light at the subwavelength scale can be exploited to engineer such nano-optical traps. This Review summarizes the recent advances in the emerging field of plasmon-based optical trapping and discusses the details of plasmon tweezers along with their potential applications to bioscience and quantum optics.

Plasmon nano-optical tweezers

A review of nanoplasmonics is given. This includes fundamentals, nanolocalization of optical energy and hot spots, ultrafast nanoplasmonics and control of the spatiotemporal nanolocalization of optical fields, and quantum nanoplasmonics (spaser and gain-assisted plasmonics). This article reviews both fundamental theoretical ideas in nanoplasmonics and selected experimental developments. It is designed both for specialists in the field and general physics readership.

Nanoplasmonics: past, present, and glimpse into future

Discrete Solitons in Optics

Optical trapping and manipulation of micrometre-sized particles was first reported in 1970. Since then, it has been successfully implemented in two size ranges: the subnanometre scale, where light-matter mechanical coupling enables cooling of atoms, ions and molecules, and the micrometre scale, where the momentum transfer resulting from light scattering allows manipulation of microscopic objects such as cells. But it has been difficult to apply these techniques to the intermediate - nanoscale - range that includes structures such as quantum dots, nanowires, nanotubes, graphene and two-dimensional crystals, all of crucial importance for nanomaterials-based applications. Recently, however, several new approaches have been developed and demonstrated for trapping plasmonic nanoparticles, semiconductor nanowires and carbon nanostructures. Here we review the state-of-the-art in optical trapping at the nanoscale, with an emphasis on some of the most promising advances, such as controlled manipulation and assembly of individual and multiple nanostructures, force measurement with femtonewton resolution, and biosensors.

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Optical trapping and manipulation of nanostructures

The implementation of optical tweezers1 at a surface opens a huge potential towards the elaboration of future lab-on-a-chip devices entirely operated with light2. The transition from conventional three-dimensional (3D) tweezers to 2D is made possible by exploiting evanescent fields bound at interfaces3,4,5. In particular, surface plasmons (SP) at metal/dielectric interfaces are expected to be excellent candidates to relax the requirements on incident power and to achieve subwavelength trapping volumes6,7. Here, we report on novel 2D SP-based optical tweezers formed by finite gold areas fabricated at a glass surface. We demonstrate that SP enable stable trapping of single dielectric beads under non-focused illumination with considerably reduced laser intensity compared with conventional optical tweezers. We show that the method can be extended to parallel trapping over any predefined pattern. Finally, we demonstrate how SP tweezers can be designed to selectively trap one type of particles out of a mixture, acting as an efficient optical sieve.

/pdf/parallel-and-selective-trapping-in-a-patterned-plasmonic-18xf3saf1w.pdf

Parallel and selective trapping in a patterned plasmonic landscape

We investigate numerically the optical forces between noble metal nanoparticles sustaining localized surface plasmon resonances. Our results first point out enhanced binding optical forces compared with dielectric nanoparticles and nonresonant metallic nanoparticles. We also show that under suitable illumination conditions, short-range forces tend to make the nanoparticles cluster, leading to intense and localized hot spots in the interstices. This effect corroborates recent experimental observations of an enhanced Raman signal in trapped metal sphere ensembles.

http://www.icfo.eu/images/publications/J07-023.pdf

Enhanced optical forces between coupled resonant metal nanoparticles.

We report on the phenomenon of trapping and switching of one-dimensional spatial solitons in Kerr-type nonlinear media with transverse periodic modulation of the refractive index. The solitons slowly radiate upon propagation along the periodic structure and are finally trapped in one of its guiding channels. The position of the output channel can be varied by small changes in the launching angle.

https://www.icfo.eu/images/publications/J04-014.pdf

Spatial soliton switching in quasi-continuous optical arrays.

We numerically investigate the optical forces exerted by an incident light beam on Rayleigh metallic particles over a dielectric substrate. In analogy with atom manipulation, we identify two different trapping regimes depending on whether the illumination is performed within the plasmon band or out of it. By adjusting the incident wavelength, the particles can be selectively guided, or immobilized, at the substrate interface.

https://www.icfo.eu/images/publications/J06-033.pdf

Tunable optical sorting and manipulation of nanoparticles via plasmon excitation

We address the dynamics of higher-order solitons in optical lattices, and predict their self-splitting into the set of their single-soliton constituents. The splitting is induced by the potential introduced by the lattice, together with the imprinting of a phase tilt onto the initial multisoliton states. The phenomenon allows the controllable generation of several coherent solitons linked via their Zakharov-Shabat eigenvalues. Application of the scheme to the generation of correlated matter waves in Bose-Einstein condensates is discussed.

https://www.icfo.eu/images/publications/J04-033.pdf

Anna S. Zelenina

Papers

Parallel and selective trapping in a patterned plasmonic landscape

Enhanced optical forces between coupled resonant metal nanoparticles.

Spatial soliton switching in quasi-continuous optical arrays.

Tunable optical sorting and manipulation of nanoparticles via plasmon excitation

Soliton Eigenvalue Control in Optical Lattices