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Armin R. Ofial
Researcher at Ludwig Maximilian University of Munich
Publications - 140
Citations - 5673
Armin R. Ofial is an academic researcher from Ludwig Maximilian University of Munich. The author has contributed to research in topics: Nucleophile & Electrophile. The author has an hindex of 34, co-authored 127 publications receiving 4997 citations. Previous affiliations of Armin R. Ofial include Darmstadt University of Applied Sciences.
Papers
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π-Nucleophilicity in Carbon−Carbon Bond-Forming Reactions
TL;DR: In this article, a new method of parametrization was proposed that facilitates a continuous extension of the data sets without the need for reparameterization of existing data, and adjusts the N and s parameters of all presently characterized π-nucleophiles (arenes, alkenes, organometallics).
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Reference Scales for the Characterization of Cationic Electrophiles and Neutral Nucleophiles
Herbert Mayr,Thorsten Bug,Matthias F. Gotta,Nicole Hering,Bernhard Irrgang,Brigitte Janker,Bernhard Kempf,Robert Loos,Armin R. Ofial,Grigoriy Ya. Remennikov,Holger Schimmel +10 more
TL;DR: Mayr et al. as discussed by the authors used correlation analysis to determine the electrophilicity parameters E and N and s as defined by the equation log k(20 °C) = s(N + E).
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Do general nucleophilicity scales exist
Herbert Mayr,Armin R. Ofial +1 more
TL;DR: In this paper, it is shown how the correlation (Eqn (1)) log k20°C = s(E + N) where s and N are nucleophile-specific parameters and E is an electrophile-specific parameter.
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Kinetics of electrophile-nucleophile combinations: A general approach to polar organic reactivity
Herbert Mayr,Armin R. Ofial +1 more
TL;DR: In this article, the same equation was employed to derive the electrophilicity parameter E for different types of car-bocations, cationic transition-metal π-complexes, typical Michael acceptors, and electron-de-ficient arenes.
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Farewell to the HSAB Treatment of Ambident Reactivity
TL;DR: It is demonstrated that the HSAB as well as the related Klopman-Salem model do not even correctly predict the behavior of the prototypes of ambident nucleophiles and, therefore, are rather misleading instead of useful guides.