Showing papers by "Bizhou Lin published in 2008"
TL;DR: Two reduced molybdenum(V) phosphates, (H2dien)4[CaMo12O24(OH)6(HPO4)4(PO4) 4]·nH2O (2), have been prepared under hydrothermal conditions and characterized by elemental analyses, IR, UV-vis, cyclic voltammetry and single-crystal X-ray diffraction as discussed by the authors.
18 citations
TL;DR: In this article, a two-dimensional solid, [{Cu(en)2}4(H4W12O42)]·9H2O (en =ethylenediamine), has been prepared under mild hydrothermal conditions.
16 citations
TL;DR: In this paper, two reduced molybdenum(V) phosphates, (Hen)6[K2H2O)Mo12O24(OH)6(H2PO4)3(HPO4)4(PO4)]·4H2
14 citations
TL;DR: In this paper, a Zr-intercalated MoS2 composites were used to hydrogenate nitrobenzene into aniline, which showed the formation of two distinct products depending on the employed Zr:MoS2 reaction stoichiometry and suggested mono-or bi-layer arrangements of the hydroxyl-Zr oligocations into the interlayer galleries between the host layers.
Abstract: Layered composites, Zr-intercalated MoS2, have been prepared utilizing the exfoliation and restacking properties of Li
x
MoS2 under mild conditions and characterized by X-ray powder diffraction, differential scanning calorimetry and BET surface measurements. It showed the formation of two distinct products depending on the employed Zr:MoS2 reaction stoichiometry. The interlayer expansions of about 4.4 A and 9.2 A suggested mono- or bi-layer arrangements of the hydroxyl–Zr oligocations into the interlayer galleries between the MoS2 host layers. The composites exhibit good catalytic activities in the hydrogenation of nitrobenzene into aniline, due to their intercalated structures and great specific surface areas.
10 citations
TL;DR: In this paper, a two-dimensional solid, [{Cu(en)2}4(H4W12O42)]·9H2O (en =ethylenediamine), has been prepared under mild hydrothermal conditions.
Abstract: A novel two-dimensional solid, [{Cu(en)2}4(H4W12O42)]·9H2O (en = ethylenediamine), has been prepared under mild hydrothermal conditions. Single crystal X-ray diffraction revealed that each paradodecatungstate [H4W12O42]8− cluster in the title compound is connected with its four adjacent clusters through eight {Cu(en)2}2+ bridging groups into a two-dimensional layered structure. Its cyclic voltammetric behavior in aqueous electrolyte demonstrated that its modified carbon paste electrode has a good stability. A probe reaction indicated that the catalytic activity of paradodecatungstates in epoxidation of maleic anhydride has been enhanced by assembling paradodecatungstate clusters into extended structures.