Chenxia Du

TL;DR: The work enriches the cluster-based metal-organic framework portfolio, bridges the gap between silver chalcogenide/chalcogenolate clusters and metal- organic frameworks, and provides a foundation for further development of functional silver-cluster-based materials.

TL;DR: In this article, three mixed ligands metal-organic frameworks (MOFs), namely, {[Zn2(Py2TTz)2(BDC)2]·2(DMF)·0.5(H2O)}n, were synthesized under solvothermal conditions, and single-crystal X-ray diffraction analyses reveal that the three MOFs possess similar 2-fold interpenetrated three-dimensional framework structures with pcu topology.

TL;DR: In this paper, a review of cyclometallation reaction, including cyclomercuration, cyclopalladation and cycloplatination of Schiff base type of ferrocenylimines as well as the transmetallation process for cycloplayered ferrocene and the stereochemistry associated with these reactions are discussed.

TL;DR: In this article, a single-crystal structure analysis of [Cu2(bben)2(N3)4]n======¯¯¯¯¯¯¯¯[bben1,2-bis(benzylamino)ethane] revealed that the complex consists of double asymmetric μ2-1,3-azide-bridged dimeric copper(II) moieties; each copper (II) coordinates with one bben, one terminal azido, and two bridging azido ligands.

TL;DR: In this paper, the authors determined the third-order nonlinear optical properties of coordination polymers [Mn(SO4)(4,4′)-bpy)(H2O)2]n (1), and [Mm(N3)2(4, 4′-bpy)]n (2) by Z-scan technique.