介绍了Kirk—Othmer Encyclopedia of Chemical Technology（化工技术百科全书）（第五版）电子图书网络版数据库，并对该数据库使用方法和检索途径作出了说明，且结合实例简单地介绍了该数据库的检索方法。

Kirk-Othmer Encyclopedia of Chemical Technology数据库介绍及实例

The progress in NCA polymerisation combined with advanced orthogonal functionalization techniques as well as the integration with other controlled polymerisation techniques significantly widened the scope of polypeptide building blocks in a variety of material designs. Well-defined synthetic stimuli-responsive polypeptides (“smart” polypeptides) with incorporated different functionalities have been extensively explored over the past decades. Their significant potential lies in the fact that they combine natural and synthetic elements both contributing to their properties. These novel materials have potential applications in biomedicine and biotechnology including tissue engineering, drug delivery and biodiagnostics. Responsive polypeptides are capable of undergoing conformational changes and phase transition accompanied by variations in the chemical and physical changes of the polypeptides in response to an external stimulus such as biologically relevant species (i.e. biomolecules), the environment (i.e. temperature, pH), irradiation with light or exposure to a magnetic field. In this review, the recent developments including synthetic strategies and applications of synthetic stimuli-responsive homo- and block polypeptides are reviewed.

Stimuli responsive synthetic polypeptides derived from N-carboxyanhydride (NCA) polymerisation

Stereoregular Polymers and Stereospecific Polymerizations Edited by Giulio Natta and Ferdinando Danusso. (The Contributions of Giulio Natta and his School of Polymer Chemistry.) Vol. 1: Pp. xxii + 1 + 466. Vol.2: Pp. xx + 467–888. (Oxford, London and New York: Pergamon Press, Ltd., 1967.) 315s. net per set of two volumes. Heteroatom Ring Systems and Polymers By H. R. Allcock. Pp. xi + 401. (New York: Academic Press, Inc.; London: Academic Press, Inc. (London), Ltd., 1967.) 132s.

Advances in Polymer Science

Development of hydrophobic deep eutectic solvents for extraction of pesticides from aqueous environments

Deep Eutectic Solvents

https://pure.tue.nl/ws/files/126082077/van_Osch_et_al_Chem_Comm_2016_metal_ion_extraction.pdf

Removal of alkali and transition metal ions from water with hydrophobic deep eutectic solvents.

https://alexandria.tue.nl/openaccess/Metis238493.pdf

How controlled and versatile is N-carboxy anhydride (NCA) polymerization at 0 °C? Effect of temperature on homo-, block- and graft (co)polymerization

https://pure.tue.nl/ws/files/3910117/897220855726406.pdf

Enzymatic synthesis and preliminary evaluation as coating of sorbitol-based, hydroxy-functional polyesters with controlled molecular weights

Deep eutectic solvents (DESs) are designer solvents analogous to ionic liquids but with lower preparation cost. Most known DESs are water-miscible, but recently water-immiscible DESs have also been presented, which are a combination of hydrogen bond donors and acceptors with long hydrophobic alkyl chains (e.g., decanoic acid + quaternary ammonium salts). These hydrophobic DESs are very interesting as solvents for recovering molecules from aqueous solutions. In this study the solubility of the sugar derived molecules furfural (FF), hydroxymethylfurfural (HMF), dimethyladipate, glucose, fructose, cyclopentanediol, cyclopentanone, and tetrahydrofurfurylalcohol was experimentally screened in six different DESs (five hydrophilic and one hydrophobic) at 30–50–80 °C, for the first time. The Kamlet–Taft parameters of the DESs were also determined, and correlations with the solubility data were established. Moreover, the thermophysical properties (viscosity, decomposition temperature) of the six DESs were measured...

/pdf/thermophysical-properties-and-solubility-of-different-sugar-36oxwxi0g4.pdf

Chjt Carin Dietz

Papers

Removal of alkali and transition metal ions from water with hydrophobic deep eutectic solvents.

How controlled and versatile is N-carboxy anhydride (NCA) polymerization at 0 °C? Effect of temperature on homo-, block- and graft (co)polymerization

Enzymatic synthesis and preliminary evaluation as coating of sorbitol-based, hydroxy-functional polyesters with controlled molecular weights

Thermophysical Properties and Solubility of Different Sugar-Derived Molecules in Deep Eutectic Solvents