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Christopher J. Moulton

Researcher at University of Leeds

Publications -  10
Citations -  811

Christopher J. Moulton is an academic researcher from University of Leeds. The author has contributed to research in topics: Ring (chemistry) & Diphosphines. The author has an hindex of 6, co-authored 10 publications receiving 750 citations.

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Transition metal–carbon bonds. Part XLII. Complexes of nickel, palladium, platinum, rhodium and iridium with the tridentate ligand 2,6-bis[(di-t-butylphosphino)methyl]phenyl

TL;DR: In this paper, the bulky diphosphine 1,3-[(di-t-butylphosphino)methyl]benzene undergoes metallation very readily to give a new type of tridentate chelating system, 2,6-bis[(diphosphino),methyl]phenyl (pcp), and complexes of the types [MX(pcp)](M = Ni, Pd, or Pt; X = Cl, Br, H, C⋮CPh, or CN; M = Rh,
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Further studies on the interconversion of large ring and cyclometallated complexes of rhodium, with the diphosphines But2P(CH2)5PBut2 and But2PCH2CHCHCH2PBut2

TL;DR: Improved routes to the fluxional cyclometallated hydride were reported in this article, where improved routes for the 16-atom ring complex with carbon monoxide and sodium tetraphenylborate were reported.
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Complexes of nickel(II), palladium(II), and platinum(II) with the β-ketophosphines PBut2(CH2COR)(R = Ph or But)

TL;DR: The β-ketophosphines PBut2(CH2COR) as discussed by the authors have been prepared by treating the α-bromoketones BrCH 2COR with PBut 2H and subsequent treatment with base.