Surgical clips, and methods of use thereof, are provided for tissue approximation and attachment, and more particularly, for sealingly joining a graft vessel to a target vessel. The graft vessel has a free end and a graft vessel wall defining a graft lumen. The target vessel has a target vessel wall defining a target lumen and has an opening in the target vessel wall. The anastomosis clip includes a clip body having a distal extremity with a distal end and a proximal extremity with a proximal end. The distal end is configured to penetrate through the graft vessel wall near the free end and through the target vessel wall near the opening such that both the distal and proximal ends of the clip body are outside the graft and target vessels. At least a portion of the clip body is shapable so as to compress the graft vessel wall against the target vessel wall with the target vessel lumen in communication with the graft vessel lumen.

Surgical clips and methods for tissue approximation

The invention relates to a physiologically acceptable composition, especially a cosmetic composition, containing: at least one structuring agent selected from the group consisting of a polyorganosiloxane-containing polymer, a non-silicone-polyamide copolymer, a wax, and mixtures thereof; (b) a hydrocarbyl-functional silicone polymer; (c) optionally, at least one silicone film former; (d) optionally, at least one volatile oil; and (e) optionally, at least one pigment.

Cosmetic composition containing a polyorganosiloxane polymer

The present invention is a, solid block copolymer comprising at least two polymer end blocks A and at least one polymer interior block B wherein each A block is a polymer block resistant to sulfonation and each B block is a polymer block susceptible to sulfonation, and wherein said A and B blocks do not contain any significant levels of olefinic unsaturation. Preferably, each A block comprising one or more segments selected from polymerized (i) para-substituted styrene monomers, (ii) ethylene, (iii) alpha olefins of 3 to 18 carbon atoms; (iv) hydrogenated 1,3-cyclodiene monomers, (v) hydrogenated monomers of conjugated dienes having a vinyl content less than 35 mol percent prior to hydrogenation, (vi) acrylic esters, (vii) methacrylic esters, and (viii) mixtures thereof; and each B block comprising segments of one or more polymerized vinyl aromatic monomers selected from (i) unsubstituted styrene monomers, (ii) ortho-substituted styrene monomers, (iii) meta-substituted styrene monomers, (iv) alpha-methylstyrene, (v) 1,1-diphenylethylene, (vi) 1,2-diphenylethylene and (vii) mixtures thereof. Also claimed are processes for making such block copolymers, and the various end uses and applications for such block copolymers.

Sulfonated block copolymers, method for making same, and various uses for such block copolymers

Mono-substituted TSA precursor Si-containing film forming compositions are disclosed. The precursors have the formula: (SiH3)2N—SiH2—X, wherein X is selected from a halogen atom; an isocyanato group; an amino group; an N-containing C4-C10 saturated or unsaturated heterocycle; or an alkoxy group. Methods for forming the Si-containing film using the disclosed mono-substituted TSA precursor are also disclosed.

Si-containing film forming precursors and methods of using the same

A wireless communication method and protocol, and wireless devices and systems for stimulation, are provided for communication between a wireless device and a charging device. During active wireless charging, communications (data transmission) from the wireless device to the charging device occurs via pulse loading the receive antenna of the receiving device. Because switching regulation in the receiving device may interfere with the communications, the switching regulation is disabled during a communications window. To further reduce the likelihood of misinterpretation of signals detected in the charging device resulting from the switching regulation or noise, the data bit rate of the pulse loading communications is maintained higher than the switching regulation frequency.

Implantable device and system and method for wireless communication

Preparation of hydroxy-terminated conjugated diene polymers, particularly polybutadienes, by capping of organodilithium- and organopolylithium- terminated conjugated diene polymers or polybutadienes with lower alkylene oxide or epoxide capping agents in the presence of certain potentiating agents or catalysts exemplified particularly by small proportions of N,N,N 1 , N 1 -tetramethylenediamine (TMEDA).

Preparation of hydroxy-terminated conjugated diene polymers

A process for the preparation of hydrocarbon solutions of monofunctional amine initiators of general structures (II): M-Qn-Z-N(A(R1R2R3))2 or (IV), wherein M is defined as an alkali metal, selected from the group consisting of lithium, sodium and potassium, Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons and alkenyl substituted aromatic hydrocarbons; Z is a hydrocarbon tether group which contains 3-25 carbon atoms; A is an element selected from Group IVa of the periodic table and R?1, R2 and R3? are independently selected from hydrogen, alkyl, substituted alkyl, cycloalkyl, aryl or substituted aryl groups, m is an integer from 0 to 7, and n is an integer from 1 to 5, monofunctional amine initiators produced by the process, use of the initiators in a polymerization process and polymers produced by the polymerization process.

Functionalized amine initiators for anionic polymerization

A process for the preparation of hydrocarbon solutions of monofunctional ether initiators of the following general structure: M-Qn-Z-OA(R1R2R3) wherein M is defined as an alkali metal, selected from the group consisting of lithium, sodium and potassium, Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons and alkenylsubstituted aromatic hydrocarbons; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; A is an element selected from carbon and silicon; R?1, R2, and R3? are independently selected from hydrogen, alkyl, substitued alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and n is an integer from 1 to 5, monofunctional ethers produced by the process, use of the initiators in a polymerization process and polymers produced by the polymerization process.

Functionalized chain extended initiators for anionic polymerization

Hetero-telechelic polymers having the formula (I): FG-(Q)d-Z-J-[A(R1R2R3)]x wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R1R2R3)]x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R?1, R2 and R3? are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and cycloalkyl and substituted cycloalkyl containing 5 to 12 carbon atoms; and x is dependent on the valence of J and varies from one when J is oxygen or sulfur to two when J is nitrogen, with the proviso that J and FG are not the same, and processes for making the same.

Hetero-telechelic polymers and processes for making same

Preparation of novel organotrilithium initiators, which are soluble in hydrocarbon media, from disubstituted vinylaromatic compounds and mono- and dilithium organic compounds, said initiators being useful in the polymerization of conjugated dienes and copolymerization of these with vinylaromatic compounds.

Conrad W. Kamienski

Papers

Preparation of hydroxy-terminated conjugated diene polymers

Functionalized amine initiators for anionic polymerization

Functionalized chain extended initiators for anionic polymerization

Hetero-telechelic polymers and processes for making same

Organotrilithium polymerization initiators