Nature And Properties Of Soils

Preface.- Contributors.- List of Abbreviations.- Section 1: Basic Principles: Introduction.-Sources of Heavy Metals and Metalloids in Soils.- Chemistry of Heavy Metals and Metalloids in Soils.- Methods for the Determination of Heavy Metals and Metalloids in Soils.- Effects of Heavy Metals and Metalloids on Soil Organisms.- Soil-Plant Relationships of Heavy Metals and Metalloids.- Heavy Metals and Metalloids as Micronutrients for Plants and Animals.-Critical Loads of Heavy Metals for Soils.- Section 2: Key Heavy Metals And Metalloids: Arsenic.- Cadmium.- Chromium and Nickel.- Cobalt and Manganese.- Copper.-Lead.- Mercury.- Selenium.- Zinc.- Section 3: Other Heavy Metals And Metalloids Of Potential Environmental Significance: Antimony.- Barium.- Gold.- Molybdenum.- Silver.- Thallium.- Tin.- Tungsten.- Uranium.- Vanadium.- Glossary of Specialized Terms.- Index.

Heavy metals in soils : trace metals and metalloids in soils and their bioavailability

Heavy metals are well-known environmental pollutants due to their toxicity, persistence in the environment, and bioaccumulative nature. Their natural sources include weathering of metal-bearing rocks and volcanic eruptions, while anthropogenic sources include mining and various industrial and agricultural activities. Mining and industrial processing for extraction of mineral resources and their subsequent applications for industrial, agricultural, and economic development has led to an increase in the mobilization of these elements in the environment and disturbance of their biogeochemical cycles. Contamination of aquatic and terrestrial ecosystems with toxic heavy metals is an environmental problem of public health concern. Being persistent pollutants, heavy metals accumulate in the environment and consequently contaminate the food chains. Accumulation of potentially toxic heavy metals in biota causes a potential health threat to their consumers including humans. This article comprehensively reviews the different aspects of heavy metals as hazardous materials with special focus on their environmental persistence, toxicity for living organisms, and bioaccumulative potential. The bioaccumulation of these elements and its implications for human health are discussed with a special coverage on fish, rice, and tobacco. The article will serve as a valuable educational resource for both undergraduate and graduate students and for researchers in environmental sciences. Environmentally relevant most hazardous heavy metals and metalloids include Cr, Ni, Cu, Zn, Cd, Pb, Hg, and As. The trophic transfer of these elements in aquatic and terrestrial food chains/webs has important implications for wildlife and human health. It is very important to assess and monitor the concentrations of potentially toxic heavy metals and metalloids in different environmental segments and in the resident biota. A comprehensive study of the environmental chemistry and ecotoxicology of hazardous heavy metals and metalloids shows that steps should be taken to minimize the impact of these elements on human health and the environment.

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Environmental Chemistry and Ecotoxicology of Hazardous Heavy Metals: Environmental Persistence, Toxicity, and Bioaccumulation

China faces great challenges in protecting its soil from contamination caused by rapid industrialization and urbanization over the last three decades. Recent nationwide surveys show that 16% of the soil samples, 19% for the agricultural soils, are contaminated based on China’s soil environmental quality limits, mainly with heavy metals and metalloids. Comparisons with other regions of the world show that the current status of soil contamination, based on the total contaminant concentrations, is not worse in China. However, the concentrations of some heavy metals in Chinese soils appear to be increasing at much greater rates. Exceedance of the contaminant limits in food crops is widespread in some areas, especially southern China, due to elevated inputs of contaminants, acidic nature of the soil and crop species or cultivars prone to heavy metal accumulation. Minimizing the transfer of contaminants from soil to the food chain is a top priority. A number of options are proposed, including identification of the sources of contaminants to agricultural systems, minimization of contaminant inputs, reduction of heavy metal phytoavailability in soil with liming or other immobilizing materials, selection and breeding of low accumulating crop cultivars, adoption of appropriate water and fertilizer management, bioremediation, and change of land use to grow nonfood crops. Implementation of these strategies requires not only technological advances, but also social-economic evaluation and effective enforcement of environmental protection law.

Soil Contamination in China: Current Status and Mitigation Strategies

Review of greenhouse gas emissions from crop production systems and fertilizer management effects

A review of studies conducted in a range of plant species indicated the importance of an adequate supply of P during early crop growth and outlined plant adaptations for accessing early season P. Potential implications of the requirement for early season P in the development of management practices to optimize P supply for crop production were also discussed. Phosphorus plays a critical role in energy reactions in the plant. Deficits can influence essentially all energy requiring processes in plant metabolism. Phosphorus stress early in the growing season can restrict crop growth, which can carry through to reduce final crop yield. Deficiencies during early growth generally have a greater negative influence on crop productivity than P restrictions imposed later in growth. Plants respond to P deficiencies by adaptations that increase the likelihood of producing some viable seed. The adaptations increase the ability of the plant to access and accumulate P and include modification of rhizosphere pH, diversio...

The importance of early season phosphorus nutrition

Selection and breeding of plant cultivars to minimize cadmium accumulation.

Cadmium is a heavy metal present in soils from natural and anthropogenic sources. Plant uptake of Cd at levels present in the soil solution is dependent on a system that is largely metabolically mediated and competitive with the uptake system for Zn and possibly other metals. Much of the Cd taken up by plants is retained in the root, but a portion is translocated to the aerial portions of the plant and into the seed. The amount of Cd accumulated and translocated in plants varies with species and with cultivars within species. Soil, environmental and management factors impact on the amount of Cd accumulated in plants. Potential methods of reducing the accumulation of Cd in crops include reduction of Cd input to the soil system, site selection, management practices which decrease the concentration of Cd in the soil solution and its uptake and translocation by plants, and development and production of plant cultivars with the genetic tendency for low Cd uptake. Key words: Cadmium, fertilizers, genetics, upta...

Cadmium accumulation in crops

Nitrogen (N) is the nutrient most limiting crop production in all areas of the world and is generally applied to soil in the largest quantity. A review of the research on N fertilization management for no-till cereal production in the Canadian Great Plains, on mainly Chernozem and Gray soils, was done to illustrate the management practices which can be used to optimize the N use efficiency so as to minimize the N loss from root zone and environmental damage. Applied N is subject to loss by volatilization, immobilization, denitrification and leaching in soil and its efficiency of use by plants is governed by soil and climatic factors, fertilizer material, and soil, crop and fertilizer management practices. Overall efficiency of applied N has been <70%. Reducing tillage intensity modifies both the demand of crops for N due to changes in yield potential, and the supply of N due to changes in N cycling and losses. Consequently, it may be necessary to compensate for this by adjusting the fertilizer rate. Fertilizer use efficiency may also change with changes in tillage management, microclimate, microbial activity and distribution of fertilizer relative to crop residue. Placing the fertilizer in a band reduces contact with soil microorganisms, reducing immobilization of both ammonium (NH4) and nitrate (NO3). Banding also slows the conversion of urea to NH3 and NH4 to NO3, which can reduce losses by denitrification and leaching. The use of the urease inhibitor n-(n-butyl) thiophosphoric triamide (NBPT) shows promise in improving the efficiency of surface-applied urea-containing fertilizers in no-till systems and reducing seedling damage from seed-placed fertilizers. Ultimately, any N fertilization package has advantages and disadvantages. In selecting the optimum fertilizer management system for a farming operation, the balance between rate of application, cost and availability of equipment, soil disturbance, seedbed quality, moisture conservation, time and labor constraints and fertilizer use efficiency must be considered. The “best” management system is not fixed, but depends on the major limiting factors on each individual farm.

Nitrogen fertilization management for no-till cereal production in the Canadian Great Plains: a review

Plants require adequate P from the very early stages of growth for optimum crop production. Phosphorus supply to the crop is affected by soil P, P fertilizer management and by soil and environmental conditions influencing P phytoavailability and root growth. Phosphorus uptake in many crops is improved by associations with arbuscular mycorrhizal fungi. Cropping system and long-term input of P through fertilizers and manures can influence the amount and phytoavailability of P in the system and the development of mycorrhizal associations. Optimum yield potential requires an adequate P supply to the crop from the soil or from P additions. Where early-season P supply is low, P fertilization may improve P nutrition and crop yield potential. Alternately, under low-P conditions, encouragement of arbuscular mycorrhizal associations may enhance P uptake by crops early in the growing season, improving crop yield potential and replacing starter fertilizer P applications. Soil P supply that exceeds P requirements of t...

Cynthia A. Grant

Papers

The importance of early season phosphorus nutrition

Selection and breeding of plant cultivars to minimize cadmium accumulation.

Cadmium accumulation in crops

Nitrogen fertilization management for no-till cereal production in the Canadian Great Plains: a review

Soil and fertilizer phosphorus: Effects on plant P supply and mycorrhizal development