The nature and properties of surface-enhanced vibrational spectra of molecules adsorbed on surfaces that can enhance the absorption and the emission of electromagnetic radiation are discussed. Examples of surface-enhanced resonant Raman scattering, surface-enhanced Raman scattering in the near-infrared and surface-enhanced infrared are given. The rough surfaces used are metal island films coated with a nanometric organic film using the Langmuir-Blodgett technique or deposited by vacuum evaporation.

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Surface enhanced vibrational spectroscopy

Rayleigh-scattering cross sections and volume-scattering coefficients are computed for standard air; they incorporate the variation of the depolarization factor with wavelength. Rayleigh optical depths are then calculated for the 1962 U.S. Standard Atmosphere and for five supplementary models. Analytic formulas are derived for each of the parameters listed. The new optical depths can be 1.3% lower to 3% higher at midvisible wavelengths and up to 10% higher in the UV region compared with previous calculations, in which a constant or incorrect depolarization factor was used. The dispersion of the depolarization factor is also shown to affect the Rayleigh phase function slightly, by approximately 1% in the forward, backscattered, and 90° scattering-angle directions.

Rayleigh-scattering calculations for the terrestrial atmosphere

Preface 1. Basic properties of radiation, atmospheres and oceans 2. Basic state variables 3. Interaction of radiation with matter 4. Formulation of radiative transfer problems 5. Approximate solutions of prototype problems 6. Accurate numerical solutions of prototype problems 7. Emission-dominated radiative processes 8. Radiative transfer in spectrally-complex media 9. Solar radiation driving photochemistry and photobiology 10. The role of radiation in climate Appendix 1. A primer on radiative transfer: absorption and scattering opacity Appendix 2. Stokes parameters, Poincare sphere, and the Mueller matrix Appendix 3. Nomenclature: glossary of symbols Appendix 4. Principle of reciprocity for the bidirectional reflectance Appendix 5. Isolation of the azimuth-dependence Appendix 6. The streaming term in spherical geometry Appendix 7. Reflectance and transmittance of the invariant intensity (I n2) Appendix 8. Scaling transformation for anisotropic scattering Appendix 9. Reciprocity, duality and effects of surface reflection Appendix 10. Removal of overflow problems in the intensity formulas.

Radiative Transfer in the Atmosphere and Ocean

A compact, highly robust airborne High Spectral Resolution Lidar (HSRL) that provides measurements of aerosol backscatter and extinction coefficients and aerosol depolarization at two wavelengths has been developed, tested, and deployed on nine field experiments (over 650 flight hours). A unique and advantageous design element of the HSRL system is the ability to radiometrically calibrate the instrument internally, eliminating any reliance on vicarious calibration from atmospheric targets for which aerosol loading must be estimated. This paper discusses the design of the airborne HSRL, the internal calibration and accuracy of the instrument, data products produced, and observations and calibration data from the first two field missions: the Joint Intercontinental Chemical Transport Experiment--Phase B (INTEX-B)/Megacity Aerosol Experiment--Mexico City (MAX-Mex)/Megacities Impacts on Regional and Global Environment (MILAGRO) field mission (hereafter MILAGRO) and the Gulf of Mexico Atmospheric Composition and Climate Study/Texas Air Quality Study II (hereafter GoMACCS/TexAQS II).

Airborne High Spectral Resolution Lidar for profiling aerosol optical properties

For improved analysis of Coastal Zone Color Scanner (CZCS) imagery, the radiance reflected from a planeparallel atmosphere and flat sea surface in the absence of aerosols (Rayleigh radiance) has been computed with an exact multiple scattering code, i.e., including polarization. The results indicate that the single scattering approximation normally used to compute this radiance can cause errors of up to 5% for small and moderate solar zenith angles. At large solar zenith angles, such as encountered in the analysis of high-latitude imagery, the errors can become much larger, e.g.,>10% in the blue band. The single scattering error also varies along individual scan lines. Comparison with multiple scattering computations using scalar transfer theory, i.e., ignoring polarization, show that scalar theory can yield errors of approximately the same magnitude as single scattering when compared with exact computations at small to moderate values of the solar zenith angle. The exact computations can be easily incorporated into CZCS processing algorithms, and, for application to future instruments with higher radiometric sensitivity, a scheme is developed with which the effect of variations in the surface pressure could be easily and accurately included in the exact computation of the Rayleigh radiance. Direct application of these computations to CZCS imagery indicates that accurate atmospheric corrections can be made with solar zenith angles at least as large as 65 degrees and probably up to at least 70 degrees with a more sensitive instrument. This suggests that the new Rayleigh radiance algorithm should produce more consistent pigment retrievals, particularly at high latitudes.

Exact Rayleigh scattering calculations for use with the Nimbus-7 Coastal Zone Color Scanner

By using a computer program, the authors intend to compute quantities specifying the low frequency scattering behavior of rotationally symmetric bodies which are metallic (electromagnetic scattering), soft, or hard (acoustic scattering)

http://ieeexplore.ieee.org/iel6/8/25516/01140429.pdf

D. Ahlgren

Papers

Rayleigh scattering