D
D. Bryan Sowerby
Researcher at University of Nottingham
Publications - 98
Citations - 1492
D. Bryan Sowerby is an academic researcher from University of Nottingham. The author has contributed to research in topics: Crystal structure & Antimony. The author has an hindex of 20, co-authored 98 publications receiving 1447 citations. Previous affiliations of D. Bryan Sowerby include Babeș-Bolyai University.
Papers
More filters
Journal ArticleDOI
The preparation and crystal structures of two diphenylantimony triacetate hydrolysis products: [Ph2Sb(OAc)2]2O and [(Ph8Sb4O6)·(HOAc)3]·CH2Cl2
TL;DR: Diphenylantimony triacetate undergoes ready hydrolysis to give the oxygen-bridged compound [Ph2Sb(OAc)2]2O containing seven-coordinate antimonyl(V) atoms, and [(Ph8Sb4O6)(HOAc)3] containing a non-adamantane Sb 4O6 cage as mentioned in this paper.
Journal ArticleDOI
Preparation and structures of two anionic antimony (III) mixed halides, Hpy [SbBr2Cl2] and [Hpy] 8 [Sb4Br12Cl8]
TL;DR: In this paper, the structure of two anionic antimony (III) bromide chlorides, Hpy [SbBr2Cl2] and Hpy[Sb4Br12Cl8], subject to halogen disorder, is described.
Journal ArticleDOI
Structure of the silver imidodi(sulphuryl fluoride)-benzene solvate AgN(SO2F)2·C6H6
TL;DR: The structure of the monobenzene solvate of silver imidodi(sulphuryl fluoride), AgN(SO2F)2 · C6H6, was determined from single crystal X-ray data as mentioned in this paper.
Journal ArticleDOI
Triorganoantimony(V) diorganophosphinates. Crystal and molecular structure of (diphenylphosphinato)(hydroxo)trimethylantimony(V), exhibiting a polymeric chain supramolecular self-assembly through hydrogen bonds
Cristian Silvestru,Anca Silvestru,Ionel Haiduc,D. Bryan Sowerby,Klaus H. Ebert,Hans Joachim Breunig +5 more
TL;DR: The reaction between R 3 SbCl 2 (R = Me, Ph) and R 2 PO 2 Na (R′ = R, Ph), which was investigated by IR and multinuclear (1 H, 13 C, 31 P) NMR spectroscopy, led to colorless needles identified by X-ray diffractometry as Me 3Sb(OH) [O(O)PPh 2 ], produced by partial hydrolysis as discussed by the authors.
Journal ArticleDOI
The first oxygen-bridged diorganoarsenic(V) compound: the crystal structure of AsMe2(S)OAs(S)Me2
Luminita Silaghi-Dumitrescu,Sofia I. Pascu,Ioan Silaghi-Dumitrescu,Ionel Haiduc,Martin N. Gibbons,D. Bryan Sowerby +5 more
TL;DR: The formation of the oxygen-bridged isomer 2 is unexpected and can be rationalised as resulting from either oxidation of the As(III)/As(III) form of the disulfide, (AsMe 2 S.S.M 2 ) or by an oxotropic rearrangement of 1 via a cyclic As 2 OS transition state as mentioned in this paper.