D
D. Griller
Researcher at National Research Council
Publications - 14
Citations - 590
D. Griller is an academic researcher from National Research Council. The author has contributed to research in topics: Radical & Trimethylsilyl. The author has an hindex of 8, co-authored 14 publications receiving 570 citations. Previous affiliations of D. Griller include Rice University.
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Tris(trimethylsilyl)silane as a radical-based reducing agent in synthesis
TL;DR: Tris(trimethylsily1)silane is an effective reducing agent for organic halides, selenides, xanthatee, and isocyanide, as well as an effective hydrosilylating agent for dialkyl ketones and alkenes as mentioned in this paper.
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Reduction of silicon-hydrogen bond strengths
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Tris(trimethylsilyl)silane: A catalyst for radical mediated reduction reactions
TL;DR: Tris(trimethylsilyl)silane was an effective substitute for toxic, tributyltin hydride in free radical chain reductions of organic halides.
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Solvent effects on the thermochemistry of free-radical reactions
TL;DR: In this article, the authors used photoacoustic calorimetry to measure the solvation energies of very small, polar molecules that participate in a given reaction in water for a variety of organic substrates and showed that the results suggest that solution data, measured in extremely polar solvents, can be converted to their gas-phase equivalents (and vice versa) by considering only the heats of solvation of small polar molecules.
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Rate constants for the reactions of alkyl radicals with 1,4‐cyclohexadiene
TL;DR: In this paper, an electron paramagnetic resonance (EPR) technique was used to show that simple alkyl radicals readily abstract hydrogen from 1,4-cyclohexadiene.