Vibrational spectra of the organic derivatives of the group VB elements

Organobismuth compounds : IV. Preparation and structural characteristics of triphenylbismuth(v) compounds containing a BiOBi bond

The course of the reaction between triphenylantimony dichloride and silver oxalate depends on both the solvent and temperature at which the reaction is carried out. No reaction occurs in toluene at room temperature, but on refluxing the solution, crystals of [SbPh4][SbPh2(ox)2]1[ox = oxalate(2–)], an ionic form of SbPh3(ox), are obtained. Covalent SbPh3(ox), on the other hand, is probably the initial product of reaction in methanol at room temperature, but on recrystallisation from hot methanol, crystals of a methoxy derivative, [SbPh3(OMe)]2ox 2, are obtained. Structures have been determined for both compounds. Compound 1 consists of tetrahedral [SbPh4]+ cations and octahedral [SbPh2(ox)2]– anions containing two chelating oxalate groups and phenyl groups in cis positions. The methoxy derivative 2 is centrosymmetric, with a quadridentate oxalate group and each antimony octahedrally co-ordinated to three phenyl groups, one methoxy group and two oxygens from the oxalate group. A quadridentate oxalate group is also present in (SbPh4)2ox 3, obtained from [SbPh4]Br and silver oxalate. The structure contains two essentially identical, independent, centrosymmetric molecules with antimony again in distorted-octahedral co-ordination.

Phenylantimony(V) oxalates: isolation and crystal structures of [SbPh4][SbPh2(ox)2], [SbPh3(OMe)]2ox and (SbPh4)2ox

Organoantimony compounds : VIII. Cleavage of Sb—O—Sb bonds in μ—oxybis(triphenyl -chloroantimony) and triphenylantimony oxide by methanol and acetylacetone

Organoantimony compounds: VII. Preparation and characterization of complex triorganoantimony(V) cations, R3SbL2+2

Organoantimony compounds of the type R3SbX and (R3Sb)2OX, where R is methyl or phenyl, and X is a bivalent anionic group such as SeO4, CrO4, or C2O4, have been prepared. Structural characteristics ...

D. R. Ridley

Papers

Organoantimony compounds. I. Infrared spectra of some trimethyl- and triphenyl-antimony derivatives