Journal ArticleDOI
Organoantimony compounds. I. Infrared spectra of some trimethyl- and triphenyl-antimony derivatives
TLDR
In this paper, a bivalent anionic group such as SeO4, CrO4 or C2O4 has been used for the preparation of organoantimony compounds of the type R3SbX and (R 3Sb)2OX.Abstract:
Organoantimony compounds of the type R3SbX and (R3Sb)2OX, where R is methyl or phenyl, and X is a bivalent anionic group such as SeO4, CrO4, or C2O4, have been prepared. Structural characteristics ...read more
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Journal ArticleDOI
Organobismuth compounds : IV. Preparation and structural characteristics of triphenylbismuth(v) compounds containing a BiOBi bond
Ram G. Goel,H.S. Prasad +1 more
TL;DR: In this article, the structural properties of triphenylbismuth derivatives have been determined by infrared spectroscopy and conductance measurements, showing that the non-ionic structure is maintained in acetonitrile except for X = ClO4, where the X groups act as monodentate ligands.
Journal ArticleDOI
Phenylantimony(V) oxalates: isolation and crystal structures of [SbPh4][SbPh2(ox)2], [SbPh3(OMe)]2ox and (SbPh4)2ox
TL;DR: In this article, the course of the reaction between triphenylantimony dichloride and silver oxalate depends on both the solvent and temperature at which the reaction is carried out.
Journal ArticleDOI
Organoantimony compounds : VIII. Cleavage of Sb—O—Sb bonds in μ—oxybis(triphenyl -chloroantimony) and triphenylantimony oxide by methanol and acetylacetone
Ram G. Goel,Donald R. Ridley +1 more
TL;DR: SbOSb bonds in (Ph3ClSb)2O and PH3SbO are cleaved readily by methanol and acetylacetone as discussed by the authors.
Journal ArticleDOI
Organoantimony compounds: VII. Preparation and characterization of complex triorganoantimony(V) cations, R3SbL2+2
Ram G. Goel,H.S. Prasad +1 more
TL;DR: In this paper, the SbO stretching frequencies for the complex cations containing DMSO, DDSO-d 6 and Ph 3 AsO occur in the 475 to 400 cm −1 region and definite assignments cannot be made for this frequency for the complexes containing DPSO or Ph 3 PO.
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Organoantimony compounds. III. Far-infrared and Raman spectroscopic studies on triorganoantimony(V) derivatives, R3SbX2
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R. G. Goel,H. S. Prasad +1 more