Bulk metallic glasses (BMGs) have been classified according to the atomic size difference, heat of mixing (� H mix ) and period of the constituent elements in the periodic table. The BMGs discovered to date are classified into seven groups on the basis of a previous result by Inoue. The seven groups are as follows: (G-I) ETM/Ln-LTM/BM-Al/Ga, (G-II) ETM/Ln-LTM/BM-Metalloid, (G-III) Al/Ga-LTM/BMMetalloid, (G-IV) IIA-ETM/Ln-LTM/BM, (G-V) LTM/BM-Metalloid, (G-VI) ETM/Ln-LTM/BM and (G-VII) IIA-LTM/BM, where ETM, Ln, LTM, BM and IIA refer to early transition, lanthanide, late transition, group IIIB–IVB and group IIA-group metals, respectively. The main alloying element of ternary G-I, G-V and G-VII, ternary G-II and G-IV, and ternary G-VI BMGs is the largest, intermediate and smallest atomic radius compared to the other alloying elements, respectively. The main alloying element of ternary BMGs belonging to G-I, G-V, G-VI and G

Classification of Bulk Metallic Glasses by Atomic Size Difference, Heat of Mixing and Period of Constituent Elements and Its Application to Characterization of the Main Alloying Element

https://cyberleninka.org/article/n/768408.pdf

Mechanical properties of graphene and graphene-based nanocomposites

Metallic glasses have been the subject of intense scientific study since the 1960s, owing to their unique properties such as high strength, large elastic limit, high hardness, and amorphous microstructure. However, bulk metallic glasses have not been used in the high strength structural applications for which they have so much potential, owing to a highly localized failure mechanism that results in catastrophic failure during unconfined loading. In this thesis, bulk metallic glass matrix composites are designed with the combined benefits of high yield strengths and tensile ductility. This milestone is achieved by first investigating the length scale of the highly localized deformation, known as shear bands, that governs fracture in all metallic glasses. Under unconfined loading, a shear band grows to a certain length that is dependent on the fracture toughness of the glass before a crack nucleates and fracture occurs. Increasing the fracture toughness and ductility involves adding microstructural stabilization techniques that prevent shear bands from lengthening and promotes formation of multiple shear bands. To accomplish this, we develop in-situ formed bulk metallic glass matrix-composites with soft crystalline dendrites whose size and distribution are controlled through a novel semi-solid processing technique. The new alloys have a dramatically increased room-temperature ductility and a fracture toughness that appears to be similar to the toughest steels. Owing to their low modulus, the composites are therefore among the toughest known materials, a claim that has recently been confirmed independently by a fracture mechanics group. We extend our toughening strategy to a titanium-vanadium-based glass-dendrite composite system with density as low as 4.97 g/cm3. The new low-density composites rival the mechanical properties of the best structural crystalline Ti alloys. We demonstrate new processing techniques available in the highly toughened composites: room temperature cold rolling, work hardening, and thermoplastic forming. This thesis is a proven road map for developing metallic glass composites into real structural engineering materials.

Designing metallic glass matrix composites with high toughness and tensile ductility

One-dimensional carbon nanotubes and two-dimensional graphene nanosheets with unique electrical, mechanical and thermal properties are attractive reinforcements for fabricating light weight, high strength and high performance metal-matrix composites. Rapid advances of nanotechnology in recent years enable the development of advanced metal matrix nanocomposites for structural engineering and functional device applications. This review focuses on the recent development in the synthesis, property characterization and application of aluminum, magnesium, and transition metal-based composites reinforced with carbon nanotubes and graphene nanosheets. These include processing strategies of carbonaceous nanomaterials and their composites, mechanical and tribological responses, corrosion, electrical and thermal properties as well as hydrogen storage and electrocatalytic behaviors. The effects of nanomaterial dispersion in the metal matrix and the formation of interfacial precipitates on these properties are also addressed. Particular attention is paid to the fundamentals and the structure–property relationships of such novel nanocomposites.

Recent progress in the development and properties of novel metal matrix nanocomposites reinforced with carbon nanotubes and graphene nanosheets

Bulk metallic glass (BMG) formers are multicomponent alloys that vitrify with remarkable ease during solidification. Technological interest in these materials has been generated by their unique properties, which often surpass those of conventional structural materials. The metastable nature of BMGs, however, has imposed a barrier to broad commercial adoption, particularly where the processing requirements of these alloys conflict with conventional metal processing methods. Research on the crystallization of BMG formers has uncovered novel thermoplastic forming (TPF)-based processing opportunities. Unique among metal processing methods, TPF utilizes the dramatic softening exhibited by a BMG as it approaches its glass-transition temperature and decouples the rapid cooling required to form a glass from the forming step. This article reviews crystallization processes in BMG former and summarizes and compares TPF-based processing methods. Finally, an assessment of scientific and technological advancements required for broader commercial utilization of BMGs will be made.

Processing of Bulk Metallic Glass

Reinforcement with carbon nanotubes in aluminum matrix composites

Application of quasicrystalline particles as a strengthening phase in Mg–Zn–Y alloys

The reinforcing effects of carbon nanotubes (CNTs) are investigated for aluminum matrix composites. The composites present a strong bonding between CNTs and the aluminum matrix using a controlled mechanical milling process, producing a network structure of aluminum atoms around CNTs. At the same time, CNTs that are dispersed during the milling process can be located inside aluminum powders, thereby providing an easy consolidation route via thermomechanical processes. A composite containing 4.5 vol% multiwalled CNTs exhibits a yield strength of 620 MPa and fracture toughness of 61 MPa·mm1/2, the values of which are nearly 15 and seven times higher than those of the corresponding starting aluminum, respectively.

https://www.cambridge.org/core/services/aop-cambridge-core/content/view/S0884291400034166

Reinforcing effects of carbon nanotubes in structural aluminum matrix nanocomposites

Microstructure and mechanical properties of aluminum alloy 2024 (Al2024)/few-layer graphene (FLG) composites produced by ball milling and hot rolling have been investigated. The presence of dispersed FLGs with high specific surface area significantly increases the strength of the composites. The composite containing 0.7 vol.% FLGs exhibits tensile strength of 700 MPa, two times higher than that of monolithic Al2024, and around 4% elongation to failure. During plastic deformation, restricted dislocation activities and the accumulated dislocation at between FLGs may contribute to strengthening of Al2024/FLG composites.

Deformation behavior of aluminum alloy matrix composites reinforced with few-layer graphene

This study evaluated the mechanical and thermal properties of aluminum alloy 2024 (Al2024) matrix composites reinforced with multi-walled carbon nanotube (MWCNT) or few-layered graphene (FLG) in the temperature range of 250–430 °C. The Al2024/MWCNT and Al2024/FLG composites were fabricated using powder metallurgy, and the associated microstructures were observed. At 350 °C, both composites maintain high yield stress about 110 MPa, since uniform dispersion of the nano-scale reinforcements has a strong interface, hinders the dislocation movement and eutectic phase coarsening and severe softening of the matrix. The composites also show a low thermal expansion coefficient of ∼18×10−6/K. The results are respectively over ∼2.5 times higher strength and ∼20% lower CTE than those of commercial Al alloy used as piston material (AlSi12CuMgNi).

Donghyun Bae

Papers

Reinforcement with carbon nanotubes in aluminum matrix composites

Application of quasicrystalline particles as a strengthening phase in Mg–Zn–Y alloys

Reinforcing effects of carbon nanotubes in structural aluminum matrix nanocomposites

Deformation behavior of aluminum alloy matrix composites reinforced with few-layer graphene

Mechanical and thermal properties of nanocarbon-reinforced aluminum matrix composites at elevated temperatures