Transition metal carbides and nitrides (MXenes), a family of two-dimensional (2D) inorganic compounds, are materials composed of a few atomic layers of transition metal carbides, nitrides, or carbonitrides. Ti3C2, the first 2D layered MXene, was isolated in 2011. This material, which is a layered bulk material analogous to graphite, was derived from its 3D phase, Ti3AlC2 MAX. Since then, material scientists have either determined or predicted the stable phases of >200 different MXenes based on combinations of various transition metals such as Ti, Mo, V, Cr, and their alloys with C and N. Extensive experimental and theoretical studies have shown their exciting potential for energy conversion and electrochemical storage. To this end, we comprehensively summarize the current advances in MXene research. We begin by reviewing the structure types and morphologies and their fabrication routes. The review then discusses the mechanical, electrical, optical, and electrochemical properties of MXenes. The focus then turns to their exciting potential in energy storage and conversion. Energy storage applications include electrodes in rechargeable lithium- and sodium-ion batteries, lithium-sulfur batteries, and supercapacitors. In terms of energy conversion, photocatalytic fuel production, such as hydrogen evolution from water splitting, and carbon dioxide reduction are presented. The potential of MXenes for the photocatalytic degradation of organic pollutants in water, such as dye waste, is also addressed, along with their promise as catalysts for ammonium synthesis from nitrogen. Finally, their application potential is summarized.

Applications of 2D MXenes in energy conversion and storage systems

Heterocyclic pyrrole molecules are in situ aligned and polymerized in the -absence of an oxidant between layers of the 2D Ti3C2Tx (MXene), resulting in high volumetric and gravimetric capacitances with capacitance retention of 92% after 25,000 cycles at a 100 mV s(-1) scan rate.

Pseudocapacitive Electrodes Produced By Oxidant-Free Polymerization of Pyrrole Between the Layers of 2D Titanium Carbide (MXene)

2D MXenes for Electromagnetic Shielding: A Review

MXenes refer to a family of 2D transition metal carbides/nitrides that are rich in chemistry. The first member of the family, Ti3C2Tx, was reported in 2011. Since then MXenes have opened up an exciting new field in 2D inorganic functional materials by virtue of their intrinsic electronic conductivity, superior hydrophilicity, rich surface chemistry and layered structure, as evidenced by the fact that the number of papers on MXenes has increased exponentially. The unique properties and ease of processing have positioned them as promising materials for a variety of applications including energy storage, especially for supercapacitors. In this review, we aim to summarize the current advances in MXene research on supercapacitors. We begin by reviewing various fabrication routes and their influence on the structure and surface chemistry of MXenes. The structure, properties, stability, and species of layered MXenes are then introduced. The focus then turns to the capacitive energy-storage mechanisms and the factors determining the electrochemical behavior and performance in supercapacitors. Besides, various types of MXene-based supercapacitors are summarized to highlight the significance of MXenes in constructing energy storage devices. Finally, challenges and prospects in this booming field are proposed to promote further development of MXenes in supercapacitors.

Emerging 2D MXenes for supercapacitors: status, challenges and prospects.

Graphene-based composites for electrochemical energy storage

MXene films are attractive for advanced supercapacitor electrodes requiring high volumetric energy density due to their high redox capacitance combined with extremely high packing density. However, the self-restacking of MXene flakes unavoidably decreases the volumetric performance, mass loading, and rate capability. Herein, a simple strategy is developed to prepare a flexible and free-standing modified MXene/holey graphene film by filtration of the alkalized MXene and holey graphene oxide dispersions, followed by a mild annealing treatment. After terminal groups (-F/-OH) are removed, the increased proportion of Ti atoms enables more pseudocapacitive reaction. Meanwhile, the embedded holey graphene effectively prevents the self-restacking of MXene and forms a high nanopore connectivity network, which is able to immensely accelerate the ion transport and shorten transport pathways for both ion and electron. When applied as electrode materials for supercapacitors, it can deliver an ultrahigh volumetric capacitance (1445 F cm-3) at 2 mV s-1, excellent rate capability, and high mass loading. In addition, the assembled symmetric supercapacitor demonstrates a fantastic volumetric energy density (38.6 Wh L-1), which is the highest value reported for MXene-based electrodes in aqueous electrolytes. This work opens a new avenue for the further exploration of MXene materials in energy storage devices.

https://www.onlinelibrary.wiley.com/doi/epdf/10.1002/advs.201800750

Modified MXene/Holey Graphene Films for Advanced Supercapacitor Electrodes with Superior Energy Storage

A lightweight and conductive MXene/graphene hybrid foam for superior electromagnetic interference shielding


 Inorganic aerogels have exhibited many superior characteristics with extensive applications, but still plagued a nearly century-old tradeoff between their mechanical and thermal properties. When reducing the thermal conductivity by ultralow density, inorganic aerogels generally suffer from large fragility due to their brittle nature or weak joint crosslinking, while enhancing the mechanical robustness by material design and structural engineering, they easily sacrifice the thermal insulation and stability. Here, we report a chemically bonded multi-nanolayer design and synthesis of a graphene/amorphous boron nitride aerogel to address this typical tradeoff to further enhance the mechanical and thermal properties. Attributed to the chemically bonded interface and coupled toughening effect, our aerogels display a low density of 0.8 mg cm−3 with ultrahigh flexibility (elastic compressive strain up to 99% and bending strain up to 90%), and exceptional thermostability (strength degradation < 3% after sharp thermal shocks), as well as the lowest thermal conductivities in vacuum (only 1.57 mW m−1 K−1 at room temperature and 10.39 mW m−1 K−1 at 500°C) among solid materials to date. This unique combination of mechanical and thermal properties offers an attractive material system for thermal superinsulation at extreme conditions.

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Duola Wang

Papers

Modified MXene/Holey Graphene Films for Advanced Supercapacitor Electrodes with Superior Energy Storage

A lightweight and conductive MXene/graphene hybrid foam for superior electromagnetic interference shielding

Chemically bonded multi-nanolayer inorganic aerogel with a record-low thermal conductivity in a vacuum