E
E. A. Chernyshev
Researcher at Russian Academy of Sciences
Publications - 46
Citations - 67
E. A. Chernyshev is an academic researcher from Russian Academy of Sciences. The author has contributed to research in topics: Trimethylsilyl & Organosilicon. The author has an hindex of 5, co-authored 46 publications receiving 64 citations.
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Journal ArticleDOI
Synthesis of cyclic polysulfides by the reaction of trimethylvinylsilane with S8 in the presence of Fe3(CO)12
E. A. Chernyshev,O. V. Kuz'min,A.V. Lebedev,A. I. Gusev,N. I. Kirillova,N. S. Nametkin,V. D. Tyurin,A.M. Krapivin,N.A. Kubasova +8 more
TL;DR: In this paper, the reaction of trimethylvinylsilane with S8 in the presence of Fe3(CO)12 yielded the following compounds: S2Fe2(CO), S 2Fe3 (CO)9, 1-trimethylsilyl-2,3,4,5,6-pentathiacycloheptane, 1,4-di(trimethylsilyl)-2.3,6,7-tetrathiacyCLooctane.
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Synthesis of trimethylsilyl-μ-S,S′-ethylenedithiolatohexacarbonyldiiron and 1-methyl-3-trimethylsilyl-2,5-dithiacyclopentane by reaction of trimethylvinylsilane with S8 in the presence of Fe3(CO)12
E. A. Chernyshev,O. V. Kuz'min,A.V. Lebedev,A. I. Gusev,M. G. Los,N. V. Alekseev,N. S. Nametkin,V. D. Tyurin,A.M. Krapivin,N.A. Kubasova,Vladimir G. Zaikin +10 more
TL;DR: In this paper, the reaction of trimethylvinylsilane with S 8 in the presence of Fe 3 (CO) 12 led to 1-trimethylsilyl-μ-S, S′ -ethylenedithiolatohexacarbonyldiiron and 1-methyl-3trimethyclopentane.
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Novel generation of organometallic systems. Metal carbonyl complexes with silacarbacyclic π-ligands, synthetic and structural investigations
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Structures of products of the reactions of halotriorganosilanes with triethyl phosphite and with sodium dialkyl phosphites
TL;DR: In this article, the reaction of trialkyl halosilanes with triethyl phosphite at high temperatures (155-180°) goes with formation mainly of silyl-substituted tervalent phosphorus derivatives, which readily combine with sulfur and undergo Arbuzov reaction with ethyl bromide.
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Peculiarities of coordination of silaoxaphenanthrene with the tricarbonylchromium group. Cyrstal and molecular structure of tricarbonyl[1-4a(10a)-η-10,10- dimethyl-10-sila-9-oxa-9,10-dihydrophenanthrene]chromium and tricarbonyl[5-8a(4b)-η-10,10-dimethyl-10-sila-9-oxa-9,10- dihydrophenanthrene]chromium
N. I. Kirillova,A. I. Gusev,V. A. Sharapov,O. B. Afanasova,Yu.E. Zubarev,N. V. Alekseev,E. A. Chernyshev,Yu.T. Struchtov +7 more
TL;DR: An X-ray crystal structural analysis of two tricarbonylchromium complexes formed by 10,10-dimethyl-10-sila-9-oxa-9,10dihydrophenanthrene (I) and having the same composition [ C 6 H 4 (SiMe 2 O)C 6 H4]Cr(CO)3 (II and III) was carried out as mentioned in this paper.