E
Edoardo Cesarotti
Researcher at University of Milan
Publications - 71
Citations - 1162
Edoardo Cesarotti is an academic researcher from University of Milan. The author has contributed to research in topics: Catalysis & Ruthenium. The author has an hindex of 19, co-authored 71 publications receiving 1098 citations.
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Journal ArticleDOI
New Class of Chiral Diphosphine Ligands for Highly Efficient Transition Metal-Catalyzed Stereoselective Reactions: The Bis(diphenylphosphino) Five-membered Biheteroaryls.
Tiziana Benincori,Elisabetta Brenna,Franco Sannicolò,Licia Trimarco,Patrizia Antognazza,Edoardo Cesarotti,Francesco Demartin,Tullio Pilati +7 more
TL;DR: The synthesis and application of three examples of a new class of chiral (C(2)) atropisomeric diphosphines characterized by two interconnected five-membered heteroaromatic rings, with hindered rotation around the interanular bond, are described.
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2,2',5,5'-tetramethyl-4,4'-bis(diphenylphoshino)-3,3'-bithiophene: a new, very efficient, easily accessible, chiral biheteroaromatic ligand for homogeneous stereoselective catalysis
TL;DR: The four-step straightforward synthesis of enantiopure (+)- and (-)-2,2',5,5'-tetramethyl-4,4'-bis-(diphenylphoshino)-3,3'-bithiophene (tetraMe-BITIOP), a new C2-symmetry chelating ligand for transition metals, is described, starting from 2,5-dimethylthiophene.
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Chiral atropisomeric five-membered biheteroaromatic diphosphines: new ligands of the bibenzimidazole and biindole series
Tiziana Benincori,Elisabetta Brenna,Franco Sannicolò,Licia Trimarco,Patrizia Antognazza,Edoardo Cesarotti,Francesco Demartin,Tullio Pilati,Gianni Zotti +8 more
TL;DR: In this article, two chiral atropisomeric biheteroaromatic diphosphines are described: 2,2′-bis(diphenylphosphino)-1,1′-bibenzimidazole (3a) and 3,3′-dimethyl-1, 1.1.
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(Diphenylphosphino)-biheteroaryls: the first example of a new class of chiral atropisomeric chelating diphosphine ligands for transition metal catalysed stereoselective reactions
Tiziana Benincori,Elisabetta Brenna,Franco Sannicolò,Licia Trimarco,Patrizia Antognazza,Edoardo Cesarotti +5 more
TL;DR: Ruthenium(II) dichloride complexes with (+)- and (−)-2,2′-bis(diphenylphosphino)-4,4′,6,6′-tetramethyl-3,3′-bibenzo[b]thiophene (1a), new chiral atropisomeric heterocyclic ligands, reduce α- and β-oxoesters to α-and β-hydroxyesters with an enantiomeric purity comparable, if not higher, to that reported for
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Schiff base complexes of oxocations—I Uranyl complexes with tetradentate optically active Schiff bases of salicylaldehyde
TL;DR: The synthesis and properties of uranyl complexes with tetradentate ligands of formula UO 2 (saldiamine) are discussed in this article, where electronic and circular dichroism spectra are also discussed.