The composition of the Earth

http://earthscience.rice.edu/wp-content/uploads/2015/09/AndersGrevesse.pdf

Abundances of the elements: Meteoritic and solar

The solar chemical composition is an important ingredient in our understanding of the formation, structure, and evolution of both the Sun and our Solar System. Furthermore, it is an essential refer ...

The Chemical Composition of the Sun

Solar photospheric and meteoritic CI chondrite abundance determinations for all elements are summarized and the best currently available photospheric abundances are selected. The meteoritic and solar abundances of a few elements (e.g., noble gases, beryllium, boron, phosphorous, sulfur) are discussed in detail. The photospheric abundances give mass fractions of hydrogen (X ¼ 0:7491), helium (Y ¼ 0:2377), and heavy elements (Z ¼ 0:0133), leading to Z=X ¼ 0:0177, which is lower than the widely used Z=X ¼ 0:0245 from previous compilations. Recent results from standard solar models considering helium and heavy-element settling imply that photospheric abundances and mass fractions are not equal to protosolar abundances (representative of solar system abundances). Protosolar elemental and isotopic abundances are derived from photospheric abundances by considering settling effects. Derived protosolar mass fractions are X0 ¼ 0:7110, Y0 ¼ 0:2741, and Z0 ¼ 0:0149. The solar system and photospheric abundance tables are used to compute self-consistent sets of condensation temperatures for all elements. Subject headings: astrochemistry — meteors, meteoroids — solar system: formation — Sun: abundances — Sun: photosphere

/pdf/solar-system-abundances-and-condensation-temperatures-of-the-f7u38sk0l8.pdf

Solar System Abundances and Condensation Temperatures of the Elements

Stellar physics and evolution calculations enable a broad range of research in astrophysics. Modules for Experiments in Stellar Astrophysics (MESA) is a suite of open source, robust, efficient, thread-safe libraries for a wide range of applications in computational stellar astrophysics. A one-dimensional stellar evolution module, MESAstar, combines many of the numerical and physics modules for simulations of a wide range of stellar evolution scenarios ranging from very low mass to massive stars, including advanced evolutionary phases. MESAstar solves the fully coupled structure and composition equations simultaneously. It uses adaptive mesh refinement and sophisticated timestep controls, and supports shared memory parallelism based on OpenMP. State-of-the-art modules provide equation of state, opacity, nuclear reaction rates, element diffusion data, and atmosphere boundary conditions. Each module is constructed as a separate Fortran 95 library with its own explicitly defined public interface to facilitate independent development. Several detailed examples indicate the extensive verification and testing that is continuously performed and demonstrate the wide range of capabilities that MESA possesses. These examples include evolutionary tracks of very low mass stars, brown dwarfs, and gas giant planets to very old ages; the complete evolutionary track of a 1 M ☉ star from the pre-main sequence (PMS) to a cooling white dwarf; the solar sound speed profile; the evolution of intermediate-mass stars through the He-core burning phase and thermal pulses on the He-shell burning asymptotic giant branch phase; the interior structure of slowly pulsating B Stars and Beta Cepheids; the complete evolutionary tracks of massive stars from the PMS to the onset of core collapse; mass transfer from stars undergoing Roche lobe overflow; and the evolution of helium accretion onto a neutron star. MESA can be downloaded from the project Web site (http://mesa.sourceforge.net/).

https://iopscience.iop.org/article/10.1088/0067-0049/192/1/3/pdf

Modules for Experiments in Stellar Astrophysics (MESA)

Chondrite classification, primordial matter composition and early solar system chemical processes, discussing cosmic gas condensation and refractory element fractionation

/pdf/meteorites-and-the-early-solar-system-4u5j2dm042.pdf

Meteorites and the Early Solar System

Solar-system abundances of the elements

This paper attempts to bring together and evaluate all significant evidence on the origin of meteorites. The iron meteorites seem to have formed at low pressures. Laboratory evidence shows that the absence of a Widmanstatten pattern in meteorites with > 16% Ni cannot be attributed to high pressures, but to supercooling or an unusually fast cooling rate for these meteorites, which prevented the development of a pattern. The presence of tridymite in the Steinbach siderophyre provides further, direct proof that the Widmanstatten pattern can form at pressures less than 3 kb. Neither diamond, nor cliftonite, nor cohenite are reliable pressure indicators in meteorites. Diamonds were formed by shock while cliftonite may have been derived from a cubic carbide such as Fe4C. Cohenite is apparently stabilized by kinetic rather than thermodynamic factors. Several lines of evidence suggest that the irons come from more than one parent body, perhaps as many as four. The frequency of pallasites is perfectly consistent with an origin in the transition zone between core and mantle of the parent body. “Hybrid” meteorites such as Brenham are not necessarily derived from the metal-silicate interface, but probably resulted from dendrite growth in the solidifying melt. Ordinary chondrites definitely are equilibrium assemblages rather than chance conglomerates. According to the best available evidence, Prior's rules seem to be valid. The metal particles in chondrites differentiated into kamacite and taenite in their present location, rather than in a remote earlier environment. Trace element abundances in ordinary and carbonaceous chondrites suggest that these meteorites accreted from two types of matter: an undepleted fraction that separated from its complement of gases at low temperatures, and a depleted fraction that lost its gases at high temperatures. These two fractions of primitive meteoritic matter are tentatively identified with the matrix and chondrules-plus-metal, respectively. New restrictive limits are placed on the iron-silicate fractionation in chondrites. No direct evolutionary path exists that connects the currently accepted solar abundances of Fe and Ni and the observed Fe/Si and Ni/Si ratios in chondrites. Apparently the solar abundance of iron is in error. The iron-silicate fractionation seems to have occurred while chondritic matter was in a more strongly reduced state than its present one. The U-He and K-Ar ages of hypersthene chondrites are systematically shorter than those of bronzite chondrites. Short ages are correlated with shock effects, and it seems that the hypersthene chondrites suffered reheating and partial-to-complete outgassing 0.4 AE ago. The cosmic-ray exposure ages of all classes of meteorites cluster distinctly, indicating that the meteorites were produced in a few discrete major collisions rather than by a quasi-continuum of smaller ones. The dates of the principal breakups are: irons, 0.6 and 0.9 AE; aubrites, 45 m.y.; bronzite chondrites, 4 m.y.; hypersthene chondrites, 0.025, 3, 7–13, and 16–31 m.y. All four clusters of hypersthene chondrites show evidence of severe outgassing 0.4 AE ago, which implies that most or all hypersthene chondrites come from the same parent body. As already noted by Signer and Suess, two distinct types of primordial gas occur in meteorites. Differentiated meteorites always contain unfractionated gas, while relatively undifferentiated meteorites contain fractionated gas. The former component is invariably associated with shock effects, and seems to have been derived from the solar wind. The latter component is correlated with other volatiles and seems to be a truly primitive constituent of meteoritic matter. Isotopic anomalies in the fractionated gas suggest that meteoritic matter was irradiated with ⩾ 1017 protons/cm2 at a very early stage of its history. There is very little doubt that most, if not all, meteorites come from the asteroid belt rather than from the moon. The orbits and geocentric velocities of stony meteorites resemble those of the Apollo asteroids (most of which are former members of the asteroid belt that have strayed into terrestrial space), but disagree strongly with the calculated orbits and velocities for lunar ejecta. Opik's conclusions about the difficulty of accelerating lunar debris to escape velocity represent a further argument against a lunar origin of stony meteorites. The most likely parent bodies of the meteorites are the 34 asteroids which cross the orbit of Mars. Collisional debris from these objects will remain in Mars-crossing orbits, and perturbations by Mars will inject some fraction of this material into terrestrial space. Most of the Mars asteroids, comprising 98% of the mass and 92% of the cross-section, belong to three Hirayama families (Phocaea, Desiderata, and Aethra), and an additional, previously unrecognized family. These families were apparently produced by disruption of parent asteroids ca. 104, 105, and 46 km in diameter. The size distribution and light curves of asteroids indicate that the larger asteroids are original accretions, rather than collision fragments. There is no reason to believe that the meteorites ever resided in bodies larger than Ceres (d = 770 km). Various theories on the origin of the meteorites are critically reviewed in the light of the preceding evidence. Wood's theory, which postulates a high-temperature and a low-temperature variety of primordial matter, is in best accord with the evidence. Apparently the asteroids accreted from varying proportions of these two types of material, and were then heated by extinct radioactivity produced in the early irradiation.

Origin, age, and composition of meteorites.

Primitive meteorites contain up to 400 ppm of a very fine-grained type of carbon tentatively called C-delta. Evidence is presented here that part of all of the C-delta is primary, not shock-produced, diamond formed by stellar condensation as a metastable phase. It appears that interstellar dust contains diamond.

Edward Anders

Papers

Abundances of the elements: Meteoritic and solar

Meteorites and the Early Solar System

Solar-system abundances of the elements

Origin, age, and composition of meteorites.

Interstellar diamonds in meteorites