Showing papers by "Emmanuel Chailleux published in 2022"

FT-ICR MS characterization of bio-binders for road pavement from HTL of microalgae residues

Abstract: Hydrothermal liquefaction (HTL) of microalgae-derived feedstocks into a bio-binder was investigated in the absence or presence of a catalyst. The resulting products of HTL of Scenedesmus species (sp.) residues present rheological properties close to those of a petroleum-derived bitumen. The chemical composition of the biobinder was analysed by two-dimensional gas chromatography (GCxGC-MS), gel permeation chromatography (GPC), and negative and positive-ion laser desorption/ionization FT-ICR MS to provide a complementary analysis of the biobinder and understanding of the role of catalysts. A detailed description of the heavy nitrogen compounds contained in the biobitumen is given.

Thermal Behavior of a Novel Solar Hybrid Road for Energy Harvesting

Abstract: Transportation is undergoing a radical transformation toward a novel way of thinking about road pavement: a sustainable, multifunctional infrastructure able to satisfy mobility needs, ensuring high safety standards, low carbon impact, automated detection through smart sensors, and resilience against natural and anthropogenic hazards. In this scenario, the road could also play a role for energy harvesting, thanks to the exploitation of solar radiation. The latter can be directly converted into electricity by solar cells placed under a semitransparent layer, or it can be harvested through a calorific flowing fluid. The aim of this paper is to introduce the concept of “hybrid road,” which is able to exploit both approaches. The innovative pavement is a multilayered structure composed by a semitransparent top layer made of glass aggregates bonded together thanks to a semitransparent resin, an electrical layer containing the solar cells, a porous asphalt layer for the circulation of the calorific fluid, and finally, a base waterproof layer. The hybrid road can generate electricity, contrast the heat-island effect, exploit the harvested energy to run a heat pump for heating purposes, or facilitate road deicing during winter. The present paper details experimental data obtained through energetic tests performed with a laboratory-size prototype of the hybrid road. The results show that the prototype is able to harvest around 55.2 W through the heat-transfer fluid. Furthermore, the heat exchange between water and asphalt has a cooling effect on the entire prototype.

Molecular Agglomeration Index: Quantification of the Incidence of Asphaltene Molecular Agglomeration in Aged Asphalt Binders Through Rheological Measurements

Abstract: The phase angle (φ) has long been recognized as a powerful tool to detect variations in asphalt binders’ chemistry and microstructure. A recent study applied unsupervised multivariate approaches to uncover hidden pattern structures in data sets and settled the most relevant reduced frequency to investigate the evolution of the phase angle master curve with aging. Considering that study’s findings, this paper revisits the δ-method—that is, an approach that estimates the apparent molecular weight distribution (AMWD) of a given asphalt binder based on its rheology—and proposes a simple indicator that quantifies the incidence of asphaltene molecular agglomeration named Molecular Agglomeration Index (MAI). Laboratory- and field-aged binders were tested and a limiting value for MAI indicating an increased binder cracking susceptibility is established in agreement with other failure criteria found in the literature.

Correction to: Proceedings of the RILEM International Symposium on Bituminous Materials

Abstract: In the original version of the book, the following belated corrections have been Incorporated in chapter 156 and chapter 226 as follows: Chapter 156: The author first name and last name has been changed. Chapter 226: The missing author L.D. Poulikakos has been included now. The chapter and book have been updated with the changes.