The subterranean estuary: a reaction zone of ground water and sea water

Subsidence of the Atlantic-type continental margin off New York

Present-day production of CaCO3 in tne world ocean is calculated to be about 5 billion tons (bt) per year, of which about 3 bt accumulate in sediments; the other 40% is dissolved. Nearly half of the carbonate sediment accumulates on reefs, banks, and tropical shelves, and consists largely of metastable aragonite and magnesian calcite. Deep-sea carbonates, predominantly calcitic coccoliths and planktonic foraminifera, have orders of magnitude lower productivity and accumulation rates than shallow-water carbonates, but they cover orders of magnitude larger basin area. Twice as much calcium is removed from the oceans by present-day carbonate accumulation as is estimated to be brought in by rivers and hydrothermal activity (1.6 bt), suggesting that outputs have been overestimated or inputs underestimated, that one or more other inputs have not been identified, and/or that the oceans are not presently in steady state. One “missing” calcium source might be groundwater, although its present-day input is probably much smaller than that of rivers. If, as seems likely, CaCO3 accumulation presently exceeds terrestial and hydrothermal input, this imbalance presumably is offset by decreased accumulation and increased input during lowered sea level: shallow-water accumulation decreases by an order of magnitude with a 100 m drop in sea level, while groundwater influx increases because of heightened piezometric head and the diagenesis of metastable aragonite and magnesian calcite from subaerially exposed shallow-water carbonates.

Production and accumulation of calcium carbonate in the ocean: Budget of a nonsteady state

The exchange of groundwater between land and sea is a major component of the hydrological cycle. This exchange, called submarine groundwater discharge (SGD), is comprised of terrestrial water mixed with sea water that has infiltrated coastal aquifers. The composition of SGD differs from that predicted by simple mixing because biogeochemical reactions in the aquifer modify its chemistry. To emphasize the importance of mixing and chemical reaction, these coastal aquifers are called subterranean estuaries. Geologists recognize this mixing zone as a site of carbonate diagenesis and dolomite formation. Biologists have recognized that terrestrial inputs of nutrients to the coastal ocean may occur through subterranean processes. Further evidence of SGD comes from the distribution of chemical tracers in the coastal ocean. These tracers originate within coastal aquifers and reach the ocean through SGD. Tracer studies reveal that SGD provides globally important fluxes of nutrients, carbon, and metals to coastal waters.

https://moritz.botany.ut.ee/~olli/eutrsem/Moore_2010.pdf

The Effect of Submarine Groundwater Discharge on the Ocean

Discharge of groundwater into the sea is widespread. Overlooking it may lead to serious misinterpretations of ecological data in studies of coastal pollution, of benthic zonation and productivity, and of the flux of dissolved substances within and between bottom sediments and over ly~ng water. Data are presented indicating that in the Perth region of Western Australia, submarine groundwater discharge delivers several times as much nltrate to coastal waters a s does river runoff.

/pdf/the-ecological-significance-of-the-submarine-discharge-of-3ewr2rv7aa.pdf

The Ecological Significance of the Submarine Discharge of Groundwater

The first broad program of scientific shallow drilling on the U.S. Atlantic continental shelf has delineated rocks of Pleistocene to Late Cretaceous age, including phosphoritic Miocene strata, widespread Eocene carbonate deposits that serve as reflective seismic markers, and several regional unconformities. Two sites, off Maryland and New Jersey, showed light hydrocarbon gases having affinity to mature petroleum. Pore fluid studies showed that relatively fresh to brackish water occurs beneath much of the Atlantic continental shelf, whereas increases in salinity off Georgla and beneath the Florida-Hatteras slope suggest buried evaporitic strata. The sediment cores showed engineering properties that range from good foundation strength to a potential for severe loss of strength through interaction between sediments and man-made structures.

U.s. Geological survey core drilling on the atlantic shelf.

/pdf/preliminary-summary-of-the-1976-atlantic-margin-coring-322cpl9dzu.pdf

Preliminary summary of the 1976 Atlantic Margin Coring Project of the U.S. Geological Survey

A deep water-resource and stratigraphic test well near the center of Nantucket Island, about 40 miles (64 km) off the New England Coast, has encountered freshwater at greater depth than predicted by the Ghyben-Herzberg principle. An uppermost lens of fresh-water, which occupies relatively permeable glacial-outwash sand and gravel to a depth of 520 ft. (158 m), is probably in hydrodynamic equilibrium with the present level of the sea and the height of the water table. However, two zones of freshwater between 730-820 ft. (222-250 m) and 900-930 ft. (274-283 m) are anomalously deep. A third zone extending from 1150-1500 ft. (350-457 m) contains slightly salty ground water (2 to 3 parts per thousand dissolved solids). Several explanations are possible, but the most likely is that large areas of the Continental Shelf were exposed to recharge by precipitation during long periods of low sea level in Pleistocene time. After the last retreat of glacial ice, seawater rapidly drowned the shelf around Nantucket Island. Since then, about 8000 years ago, the deep freshwater zones which underlie dense clay layers have not had time to adjust to a new equilibrium. Under similar circumstances freshwater may remain trapped under extensive areas of the Continental Shelf wherever clay confining beds have not permitted saltwater to intrude rapidly to new positions of hydrodynamic equilibrium. The implications are far reaching because all continental shelfs were exposed to similar hydrologic influences during Pleistocene time.

F. A. Kohout

Papers

U.s. Geological survey core drilling on the atlantic shelf.

Preliminary summary of the 1976 Atlantic Margin Coring Project of the U.S. Geological Survey

"Fresh Ground Water Stored in Aquifers Under the Continental Shelf: Implications from a Deep Test, Nantucket Island, Massachusetts"

Fresh ground water found deep beneath Nantucket Island, Masachusetts