F
F. M. Dolgushin
Researcher at A. N. Nesmeyanov Institute of Organoelement Compounds
Publications - 97
Citations - 857
F. M. Dolgushin is an academic researcher from A. N. Nesmeyanov Institute of Organoelement Compounds. The author has contributed to research in topics: Crystal structure & Ligand. The author has an hindex of 16, co-authored 97 publications receiving 814 citations.
Papers
More filters
Journal ArticleDOI
Coordination chemistry of polymercuramacrocycles. Complexation of cyclic trimeric perfluoro- o -phenylenemercury with neutral oxygeneous Lewis bases
I. A. Tikhonova,F. M. Dolgushin,K. I. Tugashov,Pavel V. Petrovskii,G. G. Furin,Vladimir B. Shur +5 more
TL;DR: In this paper, an X-ray diffraction study of cyclic trimeric perfluoro- ophenylenemercury ( o -C 6 F 4 Hg) 3 (I) has shown that the molecules of an amide are located above and below the metallacycle plane and each of them is simultaneously bonded via the oxygen atom to all Hg atoms of the cycle.
Journal ArticleDOI
Ligand effects in the hydrogenation of methacycline to doxycycline and epi-doxycycline catalysed by rhodium complexes molecular structure of the key catalyst [closo-3,3-(η2,3-C7H7CH2)-3,1,2-RhC2B9H11]
Apostolos Felekidis,M. Goblet-Stachow,Jean-François Liégeois,Bernard Pirotte,Jacques Delarge,Albert Demonceau,M. Fontaine,Alfred F. Noels,Igor T. Chizhevsky,T. V. Zinevich,Vladimir I. Bregadze,F. M. Dolgushin,A. I. Yanovsky,Yury T. Struchkov +13 more
TL;DR: In this paper, the results of the X-ray diffraction study of the best catalysts for the hydrogenation reaction of methacycline are reported, and the results for the best catalyst with carborane ligands are discussed.
Journal ArticleDOI
Reactions of diacetylene ligands with trinuclear clusters. I Reactions of 2,4-hexadiyne-1,6-diol and its dicobalthexacarbonyl derivatives with H2Os3(CO)10
M. G. Karpov,Sergey P. Tunik,V.R. Denisov,Galina L. Starova,A. B. Nikol'skii,F. M. Dolgushin,A. I. Yanovsky,Yu. T. Struchkov +7 more
TL;DR: In this paper, a single-crystal X-ray study was performed to determine the structure of a pseudo-furan ring with the C CH 3 substituent in the α-position.
Journal ArticleDOI
Complexation of cyclic trimeric perfluoro-o-phenylenemercury with nitriles. A remarkable sensitivity of the composition and structure of the resulting complexes to the nature of a nitrile
I. A. Tikhonova,F. M. Dolgushin,A. I. Yanovsky,Zoya A. Starikova,Pavel V. Petrovskii,G. G. Furin,Vladimir B. Shur +6 more
TL;DR: In this paper, a cyclic trimeric perfluoro-o-phenylenemercury (o-C6F4Hg)3(CH2CHCN) with acrylonitrile ligands was shown to have a shape of a spinning top with the equatorial girdle of which is the mercury-containing metallacycle.
Journal ArticleDOI
Synthesis of Mixed-Metal (Ru−Rh) Bimetallacarboranes via exo-nido- and closo-Ruthenacarboranes. Molecular Structures of (η4-C8H12)Rh(μ-H)Ru(PPh3)2(η5-C2B9H11) and (CO)(PPh3)Rh(μ-H)Ru(PPh3)2(η5-C2B9H11) and Their Anionic closo-Ruthenacarborane Precursors
Igor T. Chizhevsky,Irina A. Lobanova,Pavel V. Petrovskii,Vladimir I. Bregadze,F. M. Dolgushin,Alexandr I. Yanovsky,Yuri T. Struchkov,and Anatolii L. Chistyakov,Ivan V. Stankevich,Carolyn B. Knobler and,M. Frederick Hawthorne +10 more
TL;DR: In this paper, the bridging hydrogen atoms are asymmetrically disposed within these linkages, which revealed the existence of two types of bridging bonds Ru−H−Rh and B−H···Rh in these species.