Showing papers by "Friedrich Kremer published in 1996"

Evidence of dynamic heterogeneity as obtained from dielectric and brillouin light‐scattering studies of poly(n‐hexylmethacrylate)

Abstract: We report dielectric relaxation and Rayleigh-Brillouin spectroscopic measurements on the side chain polymer poly(n-hexylmethacrylate), PHMA (Tg = 268 K), exhibiting a broad glass transition region. The dielectric loss curves can be represented by single Havriliak-Negami functions in the temperature range of 260–450 K. The width of the distribution relaxation function is a decreasing function of temperature up to T = 333 K ≊ 1.24 × Tg and remains virtually constant above that temperature. This is interpreted as marking the merging of the α-process with a slow β-relaxation in agreement with the value of the cooperativity length associated with the α-mode. Hence above that temperature, the relaxation times confirm well to an Arrhenius temperature dependence. The hypersonic dispersion deduced from the Brillouin spectra (210–550 K) surprisingly peaks at temperatures near Tg which bears no relation to the main α-relaxation. This structural relaxation is rather associated with the side hexyl group motion showing striking resemblance with the hypersonic dispersion in molecular liquids. It is conceivable that the observed damping in PHMA is dynamically related to the internal plasticization effect of the hexyl group. © 1996 John Wiley & Sons, Inc.