Showing papers by "G. I. Nikishin published in 2015"
TL;DR: In this paper, the most promising methods for the synthesis of functionally substituted cyclopropanes, namely, the electrocatalytic cascade and multicomponent transformations of CH acids and also the joint electrolysis of CH acid and activated alkenes or carbonyl compounds in the presence of alkali metal halides as mediators, are discussed.
Abstract: Data on methods of electrochemical synthesis of cyclopropanes are summarized and described systematically. Direct electrochemical methods to afford cyclopropanes in both cathodic and anodic processes are considered. Among indirect electrochemical methods such as the processes employing electrogenerated bases and also those involving electrogenerated metal complexes, attention is focused on the most promising methods for the synthesis of functionally substituted cyclopropanes, namely, the electrocatalytic cascade and multicomponent transformations of CH acids and also the joint electrolysis of CH acids and activated alkenes or carbonyl compounds in the presence of alkali metal halides as mediators. The bibliography includes 62 references.
34 citations
TL;DR: The trioxolane ring is formed by the carbonyl groups located in the δ-position with respect to each other as discussed by the authors, which is the same as the trioxoline ring formed by β,δ-triketones.
Abstract: Heterogeneous reactions of β,δ-triketones with ethereal hydrogen peroxide in nonpolar solvents, catalyzed by phosphomolybdic acid, afforded mixtures of stereoisomeric ozonides, tricyclic monoperoxides, and bridged tetraoxanes. The trioxolane ring is formed by the carbonyl groups located in the δ-position with respect to each other.
18 citations