Mechanical and chemical recycling of solid plastic waste.

Recycling potential of post-consumer plastic packaging waste in Finland

Polypropylene (PP) was injection moulded several times to mimic the effect of recycling procedures. The influence of the recycling was studied by following changes in chemical structure, melt viscosity, crystallisation behaviour, and tensile and fracture properties. The main effect of recycling is the lowering of the melt viscosity, which is attributed to molecular weight decrease. Recycled PP exhibits greater crystallisation rate, higher crystallinity and equilibrium melting temperature than those measured for virgin PP. Elastic modulus and yield stress increase with the number of recycling steps. However, elongation at break and fracture toughness decrease.

Effects of recycling on the microstructure and the mechanical properties of isotactic polypropylene

Polypropylene (PP) fibers have been widely used to reinforce concrete footpaths as an alternative to steel mesh. The reinforcing effect of the PP fiber is directly proportional to its tensile strength and Young modulus. This research explored the feasibility of using an improved melt spinning and hot drawing process to produce virgin and recycled PP fibers of high mechanical properties in an industrial scale. Commercial grade granules of virgin PP, recycled PP and HPDE were mixed in different proportions in preparing five different types of fibers. All the fibers obtained high tensile strength and Young modulus. A relationship between the structural parameters and mechanical properties was then established. It was observed that the melt spinning and hot drawing process formed both a-form and b-form crystals in the PP fibers, and significantly improved crystallinity from about 50% to 80%.

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G. Neira-Velázquez

Papers

Polypropylene chain scissions and molecular weight changes in multiple extrusion

Cold plasma as an alternative method to obtain sulfur-coated PET surfaces with enhanced antibacterial performance