The surface of the Moon is a critical boundary that shapes our understanding of the Moon as a whole. All geologic mapping and remote sensing techniques utilize only the outermost portion of the Moon. Before leaving the Moon for study in our laboratories, all lunar samples that have been studied existed at or very near the surface. With the exception of the deeply probing geophysical techniques, our understanding of the interior of the Moon is derived from surficial, but not superficial, information, coupled with boundary of the lunar crust, it is the lower boundary layer of the tenuous lunar atmosphere and constitutes both a source and a sink for atmospheric gases. The surface is also where the Moon interacts with the space environment, causing changes in the physical nature of lunar materials, and provides a laboratory for the study of processes that occur on all airless bodies.

The data obtained remotely by the Galileo, Clementine, and Lunar Prospector missions, as well as data derived from lunar meteorites, have resulted in major changes to our understanding of global distributions of chemistry and rocks. This chapter summarizes the current understanding of this critical interface, the surface of the Moon, in its role as the lower boundary of the lunar atmosphere, the upper boundary of the crust, and the window through which we view, through remote sensing, the composition of the crust and the history of the Moon. In this post-Lunar Prospector time, the view of the Moon has changed, lending new perspectives to lunar samples and lunar processes. But the New View will likely remain in flux as we continue to digest the results from these recent space missions and move forward to a new era of lunar exploration.

Despite the freshness of our perspective, this is an important moment to capture, …

Understanding the Lunar Surface and Space-Moon Interactions

Plots of reflectance slope between 0402 and 0564 μm versus the intensity ratio between 0564 and 0948 μm are used to quantitatively define the mare, mare crater, upland, and bright upland crater spectral types previously presented by McCord et al (1972a) An additional spectral type, dark mantling material, has also been found Quantification of lunar spectral types allows direct comparison of the spectral units with geologic units established by the US Geological Survey, including the dark mantling material unit Unit age-color relationships are observed in the upland and mare crater spectral types However, explicit correlation in the maria between stratigraphy and color measurements is not apparent An empirical relationship is derived relating TiO2 content of the bulk lunar soils to the slope of the spectral curve between 0402 and 0564 μm The relationship is noted in both laboratory and telescopic measurements and is governed by optical absorption in the glassy material of the soils Hence the slope of the spectral curves (0402–0564 μm) may be useful as a new basis for establishing mappable geologic units on the moon Examples are presented for the mare regions

Application of Remote Spectral Reflectance Measurements to Lunar Geology Classification and Determination of Titanium Content of Lunar Soils

[1] We present the analysis of 205 spatially resolved measurements of the surface composition of Mercury from MESSENGER’s X-Ray Spectrometer. The surface footprints of these measurements are categorized according to geological terrain. Northern smooth plains deposits and the plains interior to the Caloris basin differ compositionally from older terrain on Mercury. The older terrain generally has higher Mg/Si, S/Si, and Ca/Si ratios, and a lower Al/Si ratio than the smooth plains. Mercury’s surface mineralogy is likely dominated by high-Mg mafic minerals (e.g., enstatite), plagioclase feldspar, and lesser amounts of Ca, Mg, and/or Fe sulfides (e.g., oldhamite). The compositional difference between the volcanic smooth plains and the older terrain reflects different abundances of these minerals and points to the crystallization of the smooth plains from a more chemically evolved magma source. High-degree partial melts of enstatite chondrite material provide a generally good compositional and mineralogical match for much of the surface of Mercury. An exception is Fe, for which the low surface abundance on Mercury is still higher than that of melts from enstatite chondrites and may indicate an exogenous contribution from meteoroid impacts.

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Chemical heterogeneity on Mercury's surface revealed by the MESSENGER X-Ray Spectrometer

X-rays from solar system objects

The lunar surface was mapped with respect to magnesium, aluminum, and silicon as aluminum/ silicon and magnesium/ silicon intensity ratios along the projected ground tracks swept out by the orbiting Apollo 16 spacecraft. The results confirm the observations made during the Apollo 15 flight and provide new data for a number of features not covered before. The data are consistent with the idea that the moon has a widespread differentiated crust (the highlands). The aluminum/ silicon and magnesium/ silicon concentration ratios correspond to those for anorthositic gabbros through gabbroic anorthosites or feldspathic basalts. The x-ray results suggest the occurrence of this premare crust or material similar to it at the Descartes landing site.

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Apollo 16 geochemical x-ray fluorescence experiment: preliminary report.

A number of experiments carried in orbit on the Apollo 15 and 16 spacecraft were used in the compositional mapping of the lunar surface. The observations involved measurements of secondary (fluorescent) X-rays, gamma rays and alpha particle emissions. A large scale compositional map of over 20% of the lunar surface was obtained for the first time. It was possible to demonstrate significant chemical differences between the mare and the highlands, to find specific areas of high radioactivity and to learn something about the composition of the Moon's hidden side.

Apollo 15 and 16 results of the integrated geochemical experiment.

Results of the Apollo 15 and 16 X-Ray Fluorescence Experiment

The lunar surface was mapped with respect to Mg, Al and Si as Al/Si and Mg/Si ratios along the projected ground tracks swept out by the orbiting Apollo 16 spacecraft. The results confirm the observations made during the Apollo 15 flight and provide data for a number of features not covered before. The data are consistent with the idea that the moon has a widespread differentiated crust (the highlands). The Al/Si and Mg/Si chemical ratios correspond to those for anorthositic gabbro through gabbroic anorthosites or feldspathic basalts. The X-ray results suggest the occurrence of this premare crust, or material similar to it, at the Descartes landing site.

G. Osswald

Papers

Apollo 16 geochemical x-ray fluorescence experiment: preliminary report.

Apollo 15 and 16 results of the integrated geochemical experiment.

Results of the Apollo 15 and 16 X-Ray Fluorescence Experiment

Apollo 16 geochemical X-ray fluorescene experiment: Preliminary report