G
Gyandshwar Kumar Rao
Researcher at Amity University
Publications - 66
Citations - 1765
Gyandshwar Kumar Rao is an academic researcher from Amity University. The author has contributed to research in topics: Catalysis & Palladium. The author has an hindex of 18, co-authored 57 publications receiving 1281 citations. Previous affiliations of Gyandshwar Kumar Rao include University of Ottawa & Indian Institute of Technology Delhi.
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Palladacycle containing nitrogen and selenium: highly active pre-catalyst for the Suzuki-Miyaura coupling reaction and unprecedented conversion into nano-sized Pd17Se15.
TL;DR: Newly synthesized, air and moisture insensitive palladacycle shows high catalytic activity for the Suzuki-Miyaura coupling reaction of phenylboronic acid with aryl/heteroaryl chlorides/bromides.
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Organoselenium ligands in catalysis.
TL;DR: In this review the survey of developments pertaining to the designing of such complexes, and their uses as catalysts for various organic reactions has been presented with critical analysis of present status of the subject.
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Formation and Role of Palladium Chalcogenide and Other Species in Suzuki–Miyaura and Heck C–C Coupling Reactions Catalyzed with Palladium(II) Complexes of Organochalcogen Ligands: Realities and Speculations
TL;DR: Palladium(II) complexes of organochalcogen ligands have emerged as viable alternatives to complexes of phosphine/carbene ligands for Suzuki-Miyaura and Heck C-C cross coupling reactions, as thermal stability and air and moisture sensitivity are not impediments with many of them as mentioned in this paper.
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Palladium(II)-selenated Schiff base complex catalyzed Suzuki-Miyaura coupling: dependence of efficiency on alkyl chain length of ligand.
TL;DR: The new selenated Schiff bases L1-L4 which differ in the chain lengths of non-coordinating substituents and their square planar complexes have been synthesized and characterized by multinuclei NMR and the activity of 4 which has ligand L4 has been found highest.
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Organosulphur and related ligands in Suzuki–Miyaura C–C coupling
TL;DR: Since 2000, palladium(II) complexes of organosulphur and related ligands have emerged as viable alternatives to palladium-phosphine/carbene complexes as they have sufficient thermal stability, air and moisture insensitivity and synthesis of complexes of such ligands is easy.