Electrodeposition of pyrite(FeS2) thin films for photovoltaic cells

FeS and FeS2 nanosheet films were selectively synthesized on iron substrates through one-step hydrothermal treatment of iron foil and sulfur powder in the presence or absence of hydrazine. The resulting FeSx (x = 1, 2) nanosheet films were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) and used as novel photocathodes in tandem solar cells with dye-sensitized TiO2 nanorod films as the corresponding photoanode. The photovoltaic properties of the tandem dye-sensitized solar cells were carefully studied. We found that the performance of the FeS nanosheet film photocathode was better than that of the FeS2 one in the tandem dye-sensitized solar cells. In the case of the FeS nanosheet film photocathode, a short circuit photocurrent (Isc) of 2.53 mA/cm2, an open circuit photovoltage (Voc) of 0.60 V, a fill factor (FF) of 0.31, and conversion efficiency (η) of 1.32% were obtained under an illumination of 100 mW/cm2. This study suggests that ...

Selective Synthesis of FeS and FeS2 Nanosheet Films on Iron Substrates as Novel Photocathodes for Tandem Dye-Sensitized Solar Cells

H. Dahman

Papers

Iron pyrite FeS2 for flexible solar cells

Iron pyrite films prepared by sulfur vapor transport