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Principles Of Fluorescence Spectroscopy

Lanthanide-based luminescent hybrid materials.

We present the science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems, targeting an evolution in technology, that might lead to impacts and benefits reaching into most areas of society. This roadmap was developed within the framework of the European Graphene Flagship and outlines the main targets and research areas as best understood at the start of this ambitious project. We provide an overview of the key aspects of graphene and related materials (GRMs), ranging from fundamental research challenges to a variety of applications in a large number of sectors, highlighting the steps necessary to take GRMs from a state of raw potential to a point where they might revolutionize multiple industries. We also define an extensive list of acronyms in an effort to standardize the nomenclature in this emerging field.

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Science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems

Azobenzene undergoes trans → cisisomerization when irradiated with light tuned to an appropriate wavelength. The reverse cis →transisomerization can be driven by light or occurs thermally in the dark. Azobenzene's photochromatic properties make it an ideal component of numerous molecular devices and functional materials. Despite the abundance of application-driven research, azobenzene photochemistry and the isomerization mechanism remain topics of investigation. Additional substituents on the azobenzene ring system change the spectroscopic properties and isomerization mechanism. This critical review details the studies completed to date on the 3 main classes of azobenzene derivatives. Understanding the differences in photochemistry, which originate from substitution, is imperative in exploiting azobenzene in the desired applications.

Photoisomerization in different classes of azobenzene

This chapter introduces the finite element method (FEM) as a tool for solution of classical electromagnetic problems. Although we discuss the main points in the application of the finite element method to electromagnetic design, including formulation and implementation, those who seek deeper understanding of the finite element method should consult some of the works listed in the bibliography section.

Introduction to the Finite Element Method

All-optical switching based on a subwavelength metallic grating structure containing nonlinear optical materials has been proposed and numerically investigated. Metal-dielectric composite material is used in the switching for its larger third-order nonlinear susceptibility (approximately 10(-7)esu) and ultrafast response properties. The calculated dependence of the signal light intensity on the pump light intensity shows a bistable behavior, which results in a significant switch effect. It rests on a surface plasmon's enhanced intensity-dependent change of the effective dielectric constant of Kerr nonlinear media, corresponding to a transition of the far-field transmission from a low- to high-transmission state. The study of this switching structure shows great advantages of smaller size, lower requirement of pump light intensity, and shorter switching time at approximately the picosecond level.

https://www.cct.lsu.edu/~cjmin/paper/08OL.pdf

All-optical switching in subwavelength metallic grating structure containing nonlinear optical materials.

High sensitivity is obtained at larger resonant incident angle if negative diffraction order of metallic grating is used to excite the surface plasmon. A highly sensitive grating-based surface plasmon resonance (SPR) sensor is designed for the hydrogen detection. A thin palladium (Pd) film deposited on the grating surface is used as transducer. The influences of grating period and the thickness of Pd on the performance of sensor are investigated using rigorous coupled-wave analysis (RCWA) method. The sensitivity as well as the width of the SPR curves and reflective amplitude is considered simultaneously for designing the grating-based SPR hydrogen sensor, and a set of optimized structural parameters is presented. The performance of grating-based SPR sensor is also compared with that of conventional prism-based SPR sensor.

Surface plasmon resonance hydrogen sensor based on metallic grating with high sensitivity.

We propose and demonstrate a low-threshold single-wavelength all-fiber laser generating cylindrical vector beams using a few-mode fiber Bragg grating. Both radially and azimuthally polarized beams have been generated with very good modal symmetry and polarization purity higher than 94%. The radially and azimuthally polarized modes can be switched by simply adjusting the polarization controllers built in the fiber laser cavity. This fiber laser operates at a single wavelength of 1053 nm with a 3 dB linewidth of less than 0.02 nm, signal-to-background ratio of more than 55 dB, and a threshold as low as 16 mW. A new method for the polarization purity measurement is also proposed.

Low-threshold single-wavelength all-fiber laser generating cylindrical vector beams using a few-mode fiber Bragg grating.

In this paper we report the study of the electromagnetically induced transparency (EIT)-like transmission in the bright-dark-bright plasmon resonators. It is demonstrated that the interferences between the dark plasmons excited by two bright plasmon resonators can be controlled by the incident light polarization. The constructive interference strengthens the coupling between the bright and dark resonators, leading to a more prominent EIT-like transparency window of the metamaterial. In contrary, destructive interference suppresses the coupling between the bright and dark resonators, destroying the interference pathway that forms the EIT-like transmission. Based on this observation, the plasmonic EIT switching can be realized by changing the polarization of incident light. This phenomenon may find applications in optical switching and plasmon-based information processing.

Plasmonic EIT-like switching in bright-dark-bright plasmon resonators.

A preform technique is used to prepare a step-index (SI) polymer optical fiber (POF) doped with EuDBM3Phen. The gain (5.7 dB) at 613 nm of the doped SI POF with Eu3+ content of 4000 in 106 wt., 0.4-mm core diameter, and 30-cm fiber length is observed at ambient temperature by end pumping with a YAG at 355 nm. The input signal light is ∼0.2 W. The results show the possibility of signal gain in a rare-earth-doped POF amplifier and the potential of a polymer doped with rare-earth ions as an active optical device.

Hai Ming

Papers

All-optical switching in subwavelength metallic grating structure containing nonlinear optical materials.

Surface plasmon resonance hydrogen sensor based on metallic grating with high sensitivity.

Low-threshold single-wavelength all-fiber laser generating cylindrical vector beams using a few-mode fiber Bragg grating.

Plasmonic EIT-like switching in bright-dark-bright plasmon resonators.

Optical amplification of Eu(DBM)3Phen-doped polymer optical fiber.