Showing papers by "Harold G. Freund published in 1984"
TL;DR: In this article, it was shown that various radicals exhibiting diverse ESR and ENDOR spectral characteristics are nonetheless a closely related family of alkoxy radicals, and the relationship was established by correlating the g tensor with crystal structure.
Abstract: It is shown that various radicals exhibiting diverse ESR and ENDOR spectral characteristics are nonetheless a closely related family of alkoxy radicals. The relationship is established by correlating the g tensor with crystal structure and by relating dihedral angles inferred from proton hyperfine couplings to dihedral angles inferred from the g tensor and crystal structure. The analysis also serves to demonstrate that an ESR absorption observed in x‐irradiated single crystals of uridine 5′‐monophosphate is due to an alkoxy radical.
18 citations