H
Harvey J. Wasserman
Researcher at University at Buffalo
Publications - 60
Citations - 2219
Harvey J. Wasserman is an academic researcher from University at Buffalo. The author has contributed to research in topics: Crystal structure & Tungsten. The author has an hindex of 23, co-authored 60 publications receiving 2171 citations.
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Characterization of the first examples of isolable molecular hydrogen complexes, M(CO)3(PR3)2(H2) (M = molybdenum or tungsten; R = Cy or isopropyl). Evidence for a side-on bonded dihydrogen ligand
TL;DR: In this article, the first isolable transition-metal complexes containing a coordinated dihydrogen molecule was reported, characterized by a variety of spectroscopic and structural methods to possess n/sup 2/bonded hydrogen.
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Redetermination of the crystal structure of dimanganese decacarbonyl and determination of the crystal structure of dirhenium decacarbonyl. Revised values for the manganese-manganese and rhenium-rhenium bond lengths in dimanganese decacarbonyl and dirhenium decacarbonyl
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Molecular hydrogen complexes of the transition metals. 2. Preparation, structure, and reactivity of W(CO)3(PCy3)2 and W(CO)3(P-iso-Pr3)2, .eta.2-H2 complex precursors exhibiting metal.cntdot..cntdot..cntdot.hydrogen-carbon interaction.
TL;DR: Since these molecules add dihydrogen to form stable eta/sup 2/-H/sub 2/ complexes, they afford an unprecedented opportunity to observe both H-H and C-H bond activation at a single metal center.
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Reaction of tungsten(VI) alkylidyne complexes with acetylenes to give tungstenacyclobutadiene and cyclopentadienyl complexes
TL;DR: Das Tetrachloroalkylidin wolframat reagiert mit Alkinen zu Produkten, fur die aufgrund einer Rontgenstrukturanalyse des Methyl-Derivats (RG P21/c, Z=4) die Cyclopentadienylalkin-Struktur (III) bestatigt wird.