scispace - formally typeset
Search or ask a question

Showing papers by "Heinz Gornitzka published in 2005"

Journal Article•DOI•
In Search of Cationic Germanium(II)−Transition Metal Complexes L2Ge+W(CO)5 and L2Ge+W(CO)4Ge+L2

[...]

Isabelle Saur1, Sonia Garcia Alonso1, Heinz Gornitzka1, Virginie Lemierre1, and Anna Chrostowska1, Jacques Barrau1 •
University of Pau and Pays de l'Adour1
06 May 2005-Organometallics
TL;DR: In this article, the triflate was found to be very weakly coordinating to the germanium in the solid state, and this result was confirmed by DFT calculations, and all the spectroscopic data are consistent with the L2(X)Ge ligands being good σ-donors and poor π-acceptors in these complexes, similar to the phosphine ligands in homologous R3P complexes.

41 citations

Journal Article•DOI•
Evidence for radical fragmentations from persistent singlet carbenes

[...]

Xavier Cattoën1, Karinne Miqueu1, Heinz Gornitzka1, Didier Bourissou1, Guy Bertrand1 •
University of Pau and Pays de l'Adour1
18 Feb 2005-Journal of the American Chemical Society
TL;DR: Upon warm up, persistent aminohydrazinocarbenes undergo beta-fragmentation reactions that are the first example of a homolytic fragmentation for a persistent singlet carbene.
Abstract: Upon warm up, persistent aminohydrazinocarbenes undergo β-fragmentation reactions. Experimental as well as computational evidences are reported for the involvement of radical processes. This is the first example of a homolytic fragmentation for a persistent singlet carbene.

19 citations