Showing papers by "Henry Eyring published in 1965"

Significant‐Structure Theory and Cell Theory for Two‐Dimensional Liquids of Hard Disks

Abstract: The significant‐structure theory of liquids is applied to describe a two‐dimensional liquid of hard disks. The results are in quite good agreement with the molecular‐dynamics calculations. However, the virial expansion of the equation of state is in only fair agreement with the machine calculations. Cell theory is also applied to the two‐dimensional liquid; it is found that although the agreement with the molecular‐dynamics data is poor in the liquid range, the cell theory shows good agreement in the solid region.

Significant‐Structure Theory of Binary Mixtures. II

Abstract: The significant‐structure theory has been successfully applied to the three binary systems involving carbon tetrachloride, benzene, and cyclohexane. In the first paper, the system carbon tetrachloride—cyclohexane was discussed. In this paper the other two systems, carbon tetrachloride—benzene and cyclohexane—benzene, are considered. The excess properties have been calculated on mixing at constant pressure as well as on mixing at constant volume. By taking account of the fact that the parameters in our theory are concentration dependent, a partition function for mixtures can be formulated in a similar way to those for single liquids.

Magneto-Optical Rotation of Transition-Metal Complexes

Abstract: The Faraday rotations of certain tetrahedral and octahedral transition‐metal complexes are examined by using Kramers' equation from the viewpoint of the crystal‐field theory