H
Hideki Sakurai
Researcher at Tokyo University of Science
Publications - 535
Citations - 9462
Hideki Sakurai is an academic researcher from Tokyo University of Science. The author has contributed to research in topics: Organosilicon & Trimethylsilyl. The author has an hindex of 46, co-authored 499 publications receiving 9244 citations. Previous affiliations of Hideki Sakurai include Nagasaki University & Tohoku University.
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Chemistry of organosilicon compounds
TL;DR: In this paper, two 1,2-disilacyclobutenes were prepared by the reaction of tetramethyldisilene with acetylenes, and several reactions of these new 1 2 disilacy clobutenets including oxidation, silylene insertion, iron carbonyl insertion, and addition to acetylene and dienes are reported.
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Syntheses of γ,δ-unsaturated alcohols from allylsilanes and carbonyl compounds in the presence of titanium tetrachloride
Akira Hosomi,Hideki Sakurai +1 more
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Chemistry of organosilicon compounds. 99. Conjugate addition of allylsilanes to .alpha.,.beta.-enones. A New method of stereoselective introduction of the angular allyl group in fused cyclic .alpha.,.beta.-enones
Akira Hosomi,Hideki Sakurai +1 more
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REACTIONS OF ALLYLSILANES AND APPLICATION TO ORGANIC SYNThESIS
TL;DR: In this article, the double bond of allylsilanes was shown to have high nucleophilicity, which can be used in organic synthesis and conjugate addition to n,3-eno-nes to give 6,c-enones exclusively.
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Novel anionic polymerization of masked disilenes to polysilylene high polymers and block copolymers
TL;DR: In this article, the authors describe an entirely novel method of preparing polysilylenes based on anionic polymerization of masked disilenes, which is an alternative to the Wurtz-type coupling reactions of dichlorodialkylsilanes.