How to effectively utilize low and medium temperature energy is one of the solutions to alleviate the energy shortage and environmental pollution problems. In the past twenty years, because of its feasibility and reliability, organic Rankine cycle has received widespread attentions and researches. In this paper, it reviews the selections of working fluids and expanders for organic Rankine cycle, including an analysis of the influence of working fluids' category and their thermodynamic and physical properties on the organic Rankine cycle's performance, a summary of pure and mixed working fluids' screening researches for organic Rankine cycle, a comparison of pure and mixture working fluids' applications and a discussion of all types of expansion machines' operating characteristics, which would be beneficial to select the optimal working fluid and suitable expansion machine for an effective organic Rankine cycle system.

A review of working fluid and expander selections for organic Rankine cycle

The focus of this study is to review the latest developments and technologies on waste heat recovery of exhaust gas from internal combustion engines (ICE). These include thermoelectric generators (TEG), organic Rankine cycle (ORC), six-stroke cycle IC engine and new developments on turbocharger technology. Furthermore, the study looked into the potential energy savings and performances of those technologies. The current worldwide trend of increasing energy demand in transportation sector are one of the many segments that is responsible for the growing share of fossil fuel usage and indirectly contribute to the release of harmful greenhouse gas (GHG) emissions. It is hoped that with the latest findings on exhaust heat recovery to increase the efficiency of ICEs, world energy demand on the depleting fossil fuel reserves would be reduced and hence the impact of global warming due to the GHG emissions would fade away.

Technologies to recover exhaust heat from internal combustion engines

A supercritical Rankine cycle using zeotropic mixture working fluids for the conversion of low-grade heat into power

Fluid selection and parametric optimization of organic Rankine cycle using low temperature waste heat

Potential of zeotropic mixtures as working fluids in organic Rankine cycles

The optimal evaporation temperature and working fluids for subcritical organic Rankine cycle

The performance analysis of a supercritical organic Rankine cycle system driven by exhaust heat using 18 organic working fluids is presented. Several parameters, such as the net power output, exergy efficiency, expander size parameter (SP), and heat exchanger requirement of evaporator and the condenser, were used to evaluate the performance of this recovery cycle and screen the working fluids. The results reveal that in most cases, raising the expander inlet temperature is helpful to improve the net power output and the exergy efficiency. However, the effect of the expander inlet pressure on those parameters is related to the expander inlet temperature and working fluid used. Either lower expander inlet temperature and pressure, or higher expander inlet temperature and pressure, generally makes the net power output more. Lower expander inlet temperature results in larger total heat transfer requirement and expander size. According to the screening criteria of both the higher output and the lower investment, the following working fluids for the supercritical ORC system are recommended: R152a and R143a.

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Performance Analysis and Working Fluid Selection of a Supercritical Organic Rankine Cycle for Low Grade Waste Heat Recovery

Energy and exergy analyses of a modified combined cooling, heating, and power system using supercritical CO2

The environmental impact of organic Rankine cycle for waste heat recovery through life-cycle assessment

The subcritical Organic Rankine Cycle (ORC) with 28 working fluids for waste heat recovery is discussed in this paper. The effects of the temperature of the waste heat, the critical temperature of working fluids and the pinch temperature difference in the evaporator on the optimal evaporation temperature (OET) of the ORC have been investigated. The second law efficiency of the system is regarded as the objective function and the evaporation temperature is optimized by using the quadratic approximations method. The results show that the OET will appear for the temperature ranges investigated when the critical temperatures of working fluids are lower than the waste heat temperatures by 18 ± 5 K under the pinch temperature difference of 5 K in the evaporator. Additionally, the ORC always exhibits the OET when the pinch temperature difference in the evaporator is raised under the fixed waste heat temperature. The maximum second law efficiency will decrease with the increase of pinch temperature difference in the evaporator.

https://www.mdpi.com/1099-4300/14/3/491/pdf

Hong Gao

Papers

The optimal evaporation temperature and working fluids for subcritical organic Rankine cycle

Performance Analysis and Working Fluid Selection of a Supercritical Organic Rankine Cycle for Low Grade Waste Heat Recovery

Energy and exergy analyses of a modified combined cooling, heating, and power system using supercritical CO2

The environmental impact of organic Rankine cycle for waste heat recovery through life-cycle assessment

The Optimal Evaporation Temperature of Subcritical ORC Based on Second Law Efficiency for Waste Heat Recovery