Luminogenic materials with aggregation-induced emission (AIE) attributes have attracted much interest since the debut of the AIE concept in 2001. In this critical review, recent progress in the area of AIE research is summarized. Typical examples of AIE systems are discussed, from which their structure–property relationships are derived. Through mechanistic decipherment of the photophysical processes, structural design strategies for generating new AIE luminogens are developed. Technological, especially optoelectronic and biological, applications of the AIE systems are exemplified to illustrate how the novel AIE effect can be utilized for high-tech innovations (183 references).

Aggregation-induced emission

Aggregation-induced emission: phenomenon, mechanism and applications.

http://nathan.instras.com/documentDB/paper-44.pdf

Surface photovoltage phenomena: theory, experiment, and applications

One-dimensional (1D) ZnO nanostructures have been studied intensively and extensively over the last decade not only for their remarkable chemical and physical properties, but also for their current and future diverse technological applications. This article gives a comprehensive overview of the progress that has been made within the context of 1D ZnO nanostructures synthesized via wet chemical methods. We will cover the synthetic methodologies and corresponding growth mechanisms, different structures, doping and alloying, position-controlled growth on substrates, and finally, their functional properties as catalysts, hydrophobic surfaces, sensors, and in nanoelectronic, optical, optoelectronic, and energy harvesting devices.

/pdf/one-dimensional-zno-nanostructures-solution-growth-and-30xs4d6be7.pdf

One-dimensional ZnO nanostructures: Solution growth and functional properties

Role of Structural Factors in the Nonlinear Optical Properties of Phthalocyanines and Related Compounds

A novel class of 2-(2‘-hydroxyphenyl)benzothiazole-based (HBT-based) excited-state intramolecular proton-transfer (ESIPT) compounds, N,N‘-di[3-Hydroxy-4-(2‘-benzothiazole)phenyl]isophthalic amide (DHIA) and N,N‘-di[3-Hydroxy-4-(2‘-benzothiazole)phenyl]5-tert-butyl-isophthalic amide (DHBIA) has been feasibly synthesized and the properties of their nanoparticles in THF/H2O mixed solvent were investigated. Both compounds were found to exhibit aggregation-induced emission enhancement (AIEE) due to restricted intramolecular motion and easier intramolecular proton transfer in solid state. On identical experimental conditions, the emission of DHBIA aggregates increased more remarkably than that of DHIA. Different aggregation forms of these two organic compounds, due to the steric hindrance of a single tert-butyl group, could be responsible for the notably different degrees of the fluorescence enhancement. Their aggregation modes were investigated on the basis of time-dependent absorption, scanning electron micro...

Aggregation-induced emission enhancement of 2-(2'-hydroxyphenyl)benzothiazole-based excited-state intramolecular proton-transfer compounds.

Synthesis, spectroscopic and thermal properties of a series of azo metal chelate dyes

In this work, we report on the fabrication and characteristics of light-emitting diodes based on p-GaN/i-ZnO/n-ZnO heterojunction. A 30 nm i-ZnO layer was grown on p-GaN by rf reactive magnetron sputtering, then a n-ZnO was deposited by the electron beam evaporation technique. The current-voltage characteristic of the obtained p-i-n heterojunction exhibited a diode-like rectifying behavior. Because the electrons from n-ZnO and the holes from p-GaN could be injected into a i-ZnO layer with a relatively low carrier concentration and mobility, the radiative recombination was mainly confined in i-ZnO region. As a result, an ultraviolet electro-emission at 3.21 eV, related to ZnO exciton recombination, was observed in a room-temperature electroluminescence spectrum of p-i-n heterojunction under forward bias.

Huijun Xu

Papers

Aggregation-induced emission enhancement of 2-(2'-hydroxyphenyl)benzothiazole-based excited-state intramolecular proton-transfer compounds.

Synthesis, spectroscopic and thermal properties of a series of azo metal chelate dyes

Ultraviolet electroluminescence from p-GaN/i-ZnO/n-ZnO heterojunction light-emitting diodes

Optical recording performance of thin films of phthalocyanine compounds

Application of phthalocyanine thin films in optical recording