Über die Adsorption in Lösungen

Persistent heavy metal pollution poses a major threat to all life forms in the environment due to its toxic effects. These metals are very reactive at low concentrations and can accumulate in the food web, causing severe public health concerns. Remediation using conventional physical and chemical methods is uneconomical and generates large volumes of chemical waste. Bioremediation of hazardous metals has received considerable and growing interest over the years. The use of microbial biosorbents is eco-friendly and cost effective; hence, it is an efficient alternative for the remediation of heavy metal contaminated environments. Microbes have various mechanisms of metal sequestration that hold greater metal biosorption capacities. The goal of microbial biosorption is to remove and/or recover metals and metalloids from solutions, using living or dead biomass and their components. This review discusses the sources of toxic heavy metals and describes the groups of microorganisms with biosorbent potential for heavy metal removal.

https://www.mdpi.com/1660-4601/14/1/94/pdf/1

A New Strategy for Heavy Metal Polluted Environments: A Review of Microbial Biosorbents

Environmental pollution from hazardous waste materials, organic pollutants and heavy metals, has adversely affected the natural ecosystem to the detriment of man. These pollutants arise from anthropogenic sources as well as natural disasters such as hurricanes and volcanic eruptions. Toxic metals could accumulate in agricultural soils and get into the food chain, thereby becoming a major threat to food security. Conventional and physical methods are expensive and not effective in areas with low metal toxicity. Bioremediation is therefore an eco-friendly and efficient method of reclaiming environments contaminated with heavy metals by making use of the inherent biological mechanisms of microorganisms and plants to eradicate hazardous contaminants. This review discusses the toxic effects of heavy metal pollution and the mechanisms used by microbes and plants for environmental remediation. It also emphasized the importance of modern biotechnological techniques and approaches in improving the ability of microbial enzymes to effectively degrade heavy metals at a faster rate, highlighting recent advances in microbial bioremediation and phytoremediation for the removal of heavy metals from the environment as well as future prospects and limitations. However, strict adherence to biosafety regulations must be followed in the use of biotechnological methods to ensure safety of the environment.

https://www.mdpi.com/1660-4601/14/12/1504/pdf

Microbial and Plant-Assisted Bioremediation of Heavy Metal Polluted Environments: A Review

There are number of water purification techniques but the adsorption is one of the most simplest, effective and economical method for wastewater purification. In this article a large number of solid adsorbents such as Natural adsorbents, Agricultural Wastes, Industrial wastes, Biomass, Nanoadsorbents: Carbon based nanomaterials, Nobel metal based nanomaterials, Metal oxide based nanomaterials, Spinel ferrite based nanomaterials, Nanocomposites, Dendritic polymers; Geopolymer cement have been discussed for the removal of different pollutants from waste water. Removal of Fluoride, Phosphate, Nitrate and Radionuclides from wastewater has also been reviewed in this article. Adsorption isotherm models, kinetic models, thermodynamic parameters and adsorption mechanism have also been discussed. The present article lists different type of adsorbents and reviews state-of-the-art of the removal of different pollutants from water. The efforts have been made to discuss the sources of contamination and toxicities of pollutants. Adsorption mechanisms responsible for pollutants removal by different adsorbents have been reviewed. Attempts have also been made to point out the advantages and drawbacks of adsorbents and the future research needs in the area of water purification by adsorbents.

Water purification by using Adsorbents: A Review

This paper presents an overview of the technical and economic aspects, as well as the market evolution of the Organic Rankine Cycle (ORC). This is an unconventional but very promising technology for the conversion of thermal energy, at low and medium temperatures, into electrical and/or mechanical energy on a small scale. As it makes a greater and/or more intensive use of its energy source, this technology could facilitate an electricity supply to unconnected areas, the self-production of energy, the desalination of seawater for human consumption, or even to increase the energy efficiency in the industrial sector respecting the environment. A look at the scientific publications on this topic shows an open research line, namely the selection of a suitable working fluid for these systems, since there is as yet none that provides all aspects that must be taken into account in ORCs. Furthermore, a description and an analysis of the applications of the proposed technology is carried out, specifying the main providers, which at the present time is limited mainly to the range 0.2–2 MWe with a cost of around 1 and 4 × 103 €/kWe. Lower powers are in pre-commercial status.

A technical, economical and market review of organic Rankine cycles for the conversion of low-grade heat for power generation

Industrial effluents containing heavy metals may consider a major source of contamination causes serious environmental problems. Decontamination of heavy metals from wastewater has been a challenged for a long time. A number of methods have been developed for removal of toxic metal ions from wastewaters such as precipitation, evaporation, electroplating, ion exchange, membrane processes, etc. However, these conventional technologies are providing expensive due to nonregenerable materials used, high cost and generation of toxic sludge. Biosorption is a process which represents a biotechnological innovation as well as a cost effective excellent tool for removing heavy metals from aqueous solutions. It represents a typical technique for using economical alternate biological materials for the purpose. Today, biosorption is one of the main components of environmental and bioresource technology. Application of microorganisms (specifically bacteria, algae, yeasts and fungi) as biosorbents for heavy metal removal have received growing interest due to high surface to volume ratio; large availability, rapid kinetics of adsorption and desorption and low cost. The aim of the present study is to review the removal of heavy metals from aqueous solutions using various materials of biological origin such as fungi, algae, yeast and bacterial biomass. This review discuss the significance of heavy metal removal from waste streams and provides brief overview of potential of biosorbents and biosorption technology, highlights the undelaying features of biosorption and the operation conditions such as pH, dose required, initial concentration, temperature, and treatment performance. Also sorption isotherms, sorption kinetics as well as models used to characterize biosorbent sorption are reviewed. KeywordsBiosorption; Adsorption; Heavy Metals; Wastewater; Fungi; Bacteria; Algae; Yeast

Biosorption of Heavy Metals: A Review

Solar parabolic dish Stirling engine system design, simulation, and thermal analysis

This paper presents a review of tilt angle and azimuth angles in solar energy applications. The paper involves an overview of design parameter, applications, simulations and mathematical techniques covering different usage application. The number of references analysing the tilt angle deployment in the context of the research papers of the different countries currently having operations in solar systems is much more significant. Different kinds of models and test methods of optimum tilt angle in different solar systems have been developed since 1956 which can be distinguished by their particular mathematical models or tracking techniques as shown in the latest researches. The mathematical models allows the calculation of different parameters of the solar radiation, the angle of inclination, and the optimum tilt angle of the collecting surface and the effects acting on the system.

Tilt and azimuth angles in solar energy applications – A review

Recovery of pure MnSO4∙H2O by reductive leaching of manganese from pyrolusite ore by sulfuric acid and hydrogen peroxide

The Rankine cycle is considered the most common and competitive power generation cycle to produce electricity from solar thermal energy. This paper reviews the work done on the solar Rankine cycle systems for power generation and focuses on the working fluids investigated in the literature and the application of these systems in water pumping and water desalination.

Ibrahim M. Ismail

Papers

Biosorption of Heavy Metals: A Review

Solar parabolic dish Stirling engine system design, simulation, and thermal analysis

Tilt and azimuth angles in solar energy applications – A review

Recovery of pure MnSO4∙H2O by reductive leaching of manganese from pyrolusite ore by sulfuric acid and hydrogen peroxide

A review on solar Rankine cycles: Working fluids, applications, and cycle modifications