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Ilya D. Firsin
Researcher at Ryazan State University
Publications - 20
Citations - 62
Ilya D. Firsin is an academic researcher from Ryazan State University. The author has contributed to research in topics: Tsuji–Trost reaction & Chemistry. The author has an hindex of 3, co-authored 14 publications receiving 31 citations.
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Journal ArticleDOI
Oxalamide-based bisdiamidophosphites: synthesis, coordination, and application in asymmetric metallocatalysis
Konstantin N. Gavrilov,Igor S. Mikhel,Sergey V. Zheglov,V. K. Gavrilov,I. V. Chuchelkin,Ilya D. Firsin,Kirill P. Birin,I. S. Pytskii,Ksenia A. Paseshnichenko,Victor A. Tafeenko,Vladimir V. Chernyshev,Vladimir V. Chernyshev,Alexei A. Shiryaev +12 more
TL;DR: A series of easy-to-prepare and modular chiral bisdiamidophosphites with oxalamide linkers were synthesized by means of 2D-NMR and confirmed by single-crystal X-ray diffraction as mentioned in this paper.
Journal ArticleDOI
Tartaric acid-derived chiral phosphite-type P,N-ligands: behavioural features in Pd-catalyzed asymmetric transformations
Konstantin N. Gavrilov,Sergey V. Zheglov,I. V. Chuchelkin,M. G. Maksimova,Ilya D. Firsin,Andrew N. Fitch,Vladimir V. Chernyshev,Vladimir V. Chernyshev,Alexander V. Maximychev,Alexander M. Perepukhov +9 more
TL;DR: In this paper, a practical synthesis of new phosphoramidite, phosphite and diamidophosphite P, N -ligands derived from (R, R )-tartaric acid was carried out.
Journal ArticleDOI
First P*,S-bidentate diamidophosphite ligand in Pd-catalyzed asymmetric reactions
Konstantin N. Gavrilov,I. V. Chuchelkin,Sergey V. Zheglov,Ilya D. Firsin,Vladislav S. Zimarev,V. K. Gavrilov,Alexander V. Maximychev,Alexander M. Perepukhov,Nataliya S. Goulioukina,Nataliya S. Goulioukina,Nataliya S. Goulioukina +10 more
TL;DR: In this paper, a P*,S-bidentate diamidophosphite ligand with a 1,3,2-diazaphospholidine core and an exocyclic thioether fragment provided up to 86% ee in the Pd-catalyzed alkylation of rac-(E)-1,3-diphenylallyl acetate with dimethyl malonate.
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Diamidophosphites from β-hydroxyamides: readily assembled ligands for Pd-catalyzed asymmetric allylic substitution.
I. V. Chuchelkin,Konstantin N. Gavrilov,Nataliya E. Borisova,Alexander M. Perepukhov,Alexander V. Maximychev,Sergey V. Zheglov,V. K. Gavrilov,Ilya D. Firsin,Vladislav S. Zimarev,Igor S. Mikhel,Victor A. Tafeenko,Elena Murashova,Vladimir V. Chernyshev,Vladimir V. Chernyshev,Nataliya S. Goulioukina,Nataliya S. Goulioukina,Nataliya S. Goulioukina +16 more
TL;DR: Two groups of modular chiral diamidophosphite ligands were easily synthesised from accessible N-Boc-amino alcohols and pseudodipeptides and exhibited high enantioselectivities in the Pd-mediated allylic substitution of (E)-1,3-diphenylallyl ethyl carbonate and CH2(CO2Me)2.
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Pd-Catalyzed asymmetric allylation involving bis(diamidophosphite) based on the salen-type chiral diamine
Konstantin N. Gavrilov,I. V. Chuchelkin,V. K. Gavrilov,Sergey V. Zheglov,Ilya D. Firsin,V. M. Trunina,Alexander V. Maximychev,Alexander M. Perepukhov +7 more
TL;DR: In this paper, a bis(diamidophosphite) ligand with stereogenic phosphorus atoms in the 1,3,2-diaza-phospholidine rings was synthesized based on (1R,2R)-[N, N′-bis(3-hydroxybenzylidene)]-1,2diaminocyclohexane.