The recent literature concerning the magnetocaloric effect (MCE) has been reviewed. The MCE properties have been compiled and correlations have been made comparing the behaviours of the different families of magnetic materials which exhibit large or unusual MCE values. These families include: the lanthanide (R) Laves phases (RM2, where M = Al, Co and Ni), Gd5(Si1−xGex)4 ,M n(As1−xSbx), MnFe(P1−xAsx), La(Fe13−xSix) and their hydrides and the manganites (R1−xMxMnO3, where R = lanthanide and M = Ca, Sr and Ba). The potential for use of these materials in magnetic refrigeration is discussed, including a comparison with Gd as a near room temperature active magnetic regenerator material. (Some figures in this article are in colour only in the electronic version)

https://iopscience.iop.org/article/10.1088/0034-4885/68/6/R04/pdf

Recent developments in magnetocaloric materials

In this chapter, we will restrict our attention to the ferrites and a few other closely related materials. The great interest in ferrites stems from their unique combination of a spontaneous magnetization and a high electrical resistivity. The observed magnetization results from the difference in the magnetizations of two non-equivalent sub-lattices of the magnetic ions in the crystal structure. Materials of this type should strictly be designated as “ferrimagnetic” and in some respects are more closely related to anti-ferromagnetic substances than they are to ferromagnetics in which the magnetization results from the parallel alignment of all the magnetic moments present. We shall not adhere to this special nomenclature except to emphasize effects, which are due to the existence of the sub-lattices.

Ferromagnetic materials

A new energy paradigm, consisting of greater reliance on renewable energy sources and increased concern for energy effi ciency in the total energy lifecycle, has accelerated research into energy-related technologies. Due to their ubiquity, magnetic materials play an important role in improving the effi ciency and performance of devices in electric power generation, conditioning, conversion, transportation, and other energy-use sectors of the economy. This review focuses on the state-of-the-art hard and soft magnets and magnetocaloric materials, with an emphasis on their optimization for energy applications. Specifi cally, the impact of hard magnets on electric motor and transportation technologies, of soft magnetic materials on electricity generation and conversion technologies, and of magnetocaloric materials for refrigeration technologies, are discussed. The synthesis, characterization, and property evaluation of the materials, with an emphasis on structure‐property relationships, are discussed in the context of their respective markets, as well as their potential impact on energy effi ciency. Finally, considering future bottlenecks in raw materials, options for the recycling of rare-earth intermetallics for hard magnets will be discussed.

/pdf/magnetic-materials-and-devices-for-the-21st-century-stronger-xvi5miqu1p.pdf

Magnetic materials and devices for the 21st century: Stronger, lighter, and more energy efficient

This review discusses instabilities of the Fermi-liquid state of conduction electrons in metals with particular emphasis on magnetic quantum critical points. Both the existing theoretical concepts and experimental data on selected materials are presented; with the aim of assessing the validity of presently available theory. After briefly recalling the fundamentals of Fermi-liquid theory, the local Fermi-liquid state in quantum impurity models and their lattice versions is described. Next, the scaling concepts applicable to quantum phase transitions are presented. The Hertz-Millis-Moriya theory of quantum phase transitions is described in detail. The breakdown of the latter is analyzed in several examples. In the final part experimental data on heavy-fermion materials and transition-metal alloys are reviewed and confronted with existing theory.

http://export.arxiv.org/pdf/cond-mat/0606317

Fermi-liquid instabilities at magnetic quantum phase transitions

Quantum criticality describes the collective fluctuations of matter undergoing a second-order phase transition at zero temperature. Heavy-fermion metals have in recent years emerged as prototypical systems to study quantum critical points. There have been considerable efforts, both experimental and theoretical, that use these magnetic systems to address problems that are central to the broad understanding of strongly correlated quantum matter. Here, we summarize some of the basic issues, including the extent to which the quantum criticality in heavy-fermion metals goes beyond the standard theory of order-parameter fluctuations, the nature of the Kondo effect in the quantum-critical regime, the non-Fermi-liquid phenomena that accompany quantum criticality and the interplay between quantum criticality and unconventional superconductivity. At a zero-temperature phase transition from one ordered state to another, fluctuations between the two states lead to quantum critical behaviour that can lead to unexpected physics. Metals with ‘heavy’ electrons often harbour such weird states.

Quantum criticality in heavy-fermion metals

We report the coexistence of ferromagnetic order and superconductivity in UCoGe at ambient pressure. Magnetization measurements show that UCoGe is a weak ferromagnet with a Curie temperature T(C)=3 K and a small ordered moment m(0)=0.03 micro(B). Superconductivity is observed with a resistive transition temperature T(s)=0.8 K for the best sample. Thermal-expansion and specific-heat measurements provide solid evidence for bulk magnetism and superconductivity. The proximity to a ferromagnetic instability, the defect sensitivity of T(s), and the absence of Pauli limiting, suggest triplet superconductivity mediated by critical ferromagnetic fluctuations.

/pdf/superconductivity-on-the-border-of-weak-itinerant-1vdelpdix9.pdf

Superconductivity on the Border of Weak Itinerant Ferromagnetism in UCoGe

MnFeP1−xSix compounds with x=0.10,0.20,0.24,0.28,…,0.80,1 were prepared by high-energy ball milling and solid-state reaction. The structural, magnetic, and magnetocaloric properties are investigated as a function of temperature and magnetic field. X-ray diffraction studies show that the samples in the range from x=0.28 to 0.64 adopt the hexagonal Fe2P-type structure with a small amount of second phase which increases with increasing Si content. The samples with lower Si content show the orthorhombic Co2P-type structure. Magnetic measurements show that the paramagnetic-ferromagnetic transition temperatures range from 214to377K. Of much importance is the fact that these compounds do not contain any toxic components and exhibit excellent magnetocaloric properties.

https://pure.uva.nl/ws/files/1088517/69767_301639.pdf

Structure, magnetism, and magnetocaloric properties of MnFeP1−xSix compounds

We have studied the magnetocaloric effect in MnFe(P,Si,Ge) compounds. The structural properties of the compounds were determined by x-ray diffraction. The homogeneity and the stoichiometry of the compounds were checked by electron probe microanalysis. The Curie temperature is found to be near room temperature. Specific-heat measurements made on these compounds show a first-order ferromagnetic—paramagnetic phase transition. The magnetocaloric effect derived from magnetization data shows that this effect in the MnFe(P,Si,Ge) compounds is as large as that in Gd-based compounds and MnFeP1−xAsx compounds. This means that we have succeeded in totally replacing As by (Ge,Si) in the latter compounds without losing the favorable magnetic properties. The upshot is that we have found relatively low cost and nontoxic materials for room-temperature cooling applications.

J.C.P. Klaasse

Papers

Superconductivity on the Border of Weak Itinerant Ferromagnetism in UCoGe

Structure, magnetism, and magnetocaloric properties of MnFeP1−xSix compounds

Magnetocaloric effect in MnFe(P,Si,Ge) compounds

CeCu2Ge2: Magnetic order in a Kondo lattice

Magnetic phase transition and magnetocaloric effect in Mn5-xFexSi3