Optical antennas are devices that convert freely propagating optical radiation into localized energy, and vice versa. They enable the control and manipulation of optical fields at the nanometre scale, and hold promise for enhancing the performance and efficiency of photodetection, light emission and sensing. Although many of the properties and parameters of optical antennas are similar to their radiowave and microwave counterparts, they have important differences resulting from their small size and the resonant properties of metal nanostructures. This Review summarizes the physical properties of optical antennas, provides a summary of some of the most important recent developments in the field, discusses the potential applications and identifies the future challenges and opportunities.

Antennas for light

Nano-optics of surface plasmon polaritons

Tunneling electrons from a scanning tunneling microscope (STM) were used to excite photon emission from individual porphyrin molecules adsorbed on an ultrathin alumina film grown on a NiAl(110) surface. Vibrational features were observed in the light-emission spectra that depended sensitively on the different molecular conformations and corresponding electronic states obtained by scanning tunneling spectroscopy. The high spatial resolution of the STM enabled the demonstration of variations in light-emission spectra from different parts of the molecule. These experiments realize the feasibility of fluorescence spectroscopy with the STM and enable the integration of optical spectroscopy with a nanoprobe for the investigation of single molecules.

https://science.sciencemag.org/content/sci/299/5606/542.full.pdf

Vibrationally Resolved Fluorescence Excited with Submolecular Precision

http://w0.rz-berlin.mpg.de/hjfdb/pdf/291e.pdf

Clusters and islands on oxides: from catalysis via electronics and magnetism to optics

The tip-surface region of a scanning tunneling microscope (STM) emits light when the energy of the tunneling electrons is sufficient to excite luminescent processes. These processes provide access to dynamic aspects of the local electronic structure that are not directly amenable to conventional STM experiments. From monolayer films of carbon-60 fullerenes on gold(110) surfaces, intense emission is observed when the STM tip is placed above an individual molecule. The diameter of this emission spot associated with carbon-60 is approximately 4 angstroms. These results demonstrate the highest spatial resolution of light emission to date with a scanning probe technique.

https://science.sciencemag.org/content/sci/262/5138/1425.full.pdf

Photon Emission at Molecular Resolution Induced by a Scanning Tunneling Microscope

By placing a photon detector near the tip-sample region of a scanning tunneling microscope, we have measured isochromat photon-emission spectra of polycrystalline tantalum and Si(111)7×7 at photon energies of 9.5 eV. Such spectra contain electronic-structure information comparable to inverse photoemission spectroscopy, but with high lateral/spatial resolution. The implications of this new observation are discussed.

Photon emission with the scanning tunneling microscope

SUMMARY

We have detected the light emitted from an STM at both ultraviolet (9·5 eV) and optical (1–4 eV) energies. We show that this light contains spectroscopic information on the sample surface comparable to conventional inverse photoelectric spectroscopy, but with nearly atomic spatial resolution. At optical energies we found sufficiently high intensities to allow spatial imaging of the emission probability. We propose that the high quantum efficiency is due to resonance phenomena, and present fluorescence spectra of the emitted light that support this view. We believe that atomic resolution inverse photoemission microscopy and spectroscopy will provide an important new dimension to surface studies.

Photon emission experiments with the scanning tunnelling microscope

SUMMARY

We have measured field-emission resonances (FER) to much higher quantum states than previously observed enabling fine structure in the resonance amplitudes to be investigated. We show that this electron wave interference effect carries additional information in the resonance amplitudes and energies and is sensitive to lateral tip position in a scanning tunnelling microscope experiment. We propose a new method of data analysis that can distinguish between some of the possible origins of the fine structure.

J. H. Coombs

Papers

Photon emission with the scanning tunneling microscope

Photon emission experiments with the scanning tunnelling microscope

Fine structure in field emission resonances at surfaces

Local inverse photoemission with the scanning tunneling microscope