Isotopic source signatures for atmospheric lead: the Northern Hemisphere

Tracing the transport of anthropogenic lead in the atmosphere and in soils using isotopic ratios

This paper presents a large palaeolimnological study of the pre-industrial and industrial history of atmospheric lead pollution deposition in Sweden Both lead concentrations and 206Pb/207Pb ratios have been analysed in 31 lakes covering most of Sweden, plus one lake in north-west Russia Four of the lakes have varved (annually-laminated) sediments Isotope analysis is a sensitive and effective method to distinguish pollution lead from natural catchment lead and to detect early pollution influence, because the 206Pb/207Pb ratio in unpolluted background sediments in Sweden was > 13, while that of lead from pollution, derived from ores and coal, was < 12 The sediments show a consistent picture of past temporal changes in atmospheric lead pollution These changes include: the first traces of pollution 3,500-3,000 yrs ago; a pollution peak in Greek-Roman Times (about 0 AD); lower lead fall-out between 400 and 900 AD; a significant and permanent increase in atmospheric lead fall-out from about 1000 AD; an increase with the Industrial revolution; a major increase following World War II; the maximum peak in the 1970s; and decreasing fall-out over the last decades The four varved sediments provide high-resolution records of atmospheric pollution They reveal pollution peaks about 1200 and 1530 AD which match the history of metal production in Europe According to the varve records the lead pollution level in the late 1990s had decreased beneath the level of the 1530s The pollution level 1200 AD was about 35% of the 1980s, when lead pollution was still near its all time high About 50% of the total accumulated atmospheric lead pollution deposition through time was deposited in the pre-industrial period The sediments also show a consistent picture of the geographic distribution of atmospheric lead deposition over time, with higher deposition in south Sweden and declining levels to the north, which supports the hypothesis that the main sources of pre-industrial atmospheric lead pollution in Sweden were cultural areas in mainland Europe and Great Britain

J.M. Martin

Papers

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