A comprehensive review of spatiotemporal pattern formation in systems driven away from equilibrium is presented, with emphasis on comparisons between theory and quantitative experiments. Examples include patterns in hydrodynamic systems such as thermal convection in pure fluids and binary mixtures, Taylor-Couette flow, parametric-wave instabilities, as well as patterns in solidification fronts, nonlinear optics, oscillatory chemical reactions and excitable biological media. The theoretical starting point is usually a set of deterministic equations of motion, typically in the form of nonlinear partial differential equations. These are sometimes supplemented by stochastic terms representing thermal or instrumental noise, but for macroscopic systems and carefully designed experiments the stochastic forces are often negligible. An aim of theory is to describe solutions of the deterministic equations that are likely to be reached starting from typical initial conditions and to persist at long times. A unified description is developed, based on the linear instabilities of a homogeneous state, which leads naturally to a classification of patterns in terms of the characteristic wave vector q0 and frequency ω0 of the instability. Type Is systems (ω0=0, q0≠0) are stationary in time and periodic in space; type IIIo systems (ω0≠0, q0=0) are periodic in time and uniform in space; and type Io systems (ω0≠0, q0≠0) are periodic in both space and time. Near a continuous (or supercritical) instability, the dynamics may be accurately described via "amplitude equations," whose form is universal for each type of instability. The specifics of each system enter only through the nonuniversal coefficients. Far from the instability threshold a different universal description known as the "phase equation" may be derived, but it is restricted to slow distortions of an ideal pattern. For many systems appropriate starting equations are either not known or too complicated to analyze conveniently. It is thus useful to introduce phenomenological order-parameter models, which lead to the correct amplitude equations near threshold, and which may be solved analytically or numerically in the nonlinear regime away from the instability. The above theoretical methods are useful in analyzing "real pattern effects" such as the influence of external boundaries, or the formation and dynamics of defects in ideal structures. An important element in nonequilibrium systems is the appearance of deterministic chaos. A greal deal is known about systems with a small number of degrees of freedom displaying "temporal chaos," where the structure of the phase space can be analyzed in detail. For spatially extended systems with many degrees of freedom, on the other hand, one is dealing with spatiotemporal chaos and appropriate methods of analysis need to be developed. In addition to the general features of nonequilibrium pattern formation discussed above, detailed reviews of theoretical and experimental work on many specific systems are presented. These include Rayleigh-Benard convection in a pure fluid, convection in binary-fluid mixtures, electrohydrodynamic convection in nematic liquid crystals, Taylor-Couette flow between rotating cylinders, parametric surface waves, patterns in certain open flow systems, oscillatory chemical reactions, static and dynamic patterns in biological media, crystallization fronts, and patterns in nonlinear optics. A concluding section summarizes what has and has not been accomplished, and attempts to assess the prospects for the future.

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Pattern formation outside of equilibrium

A wide variety of two- and three-dimensional physical-chemical systems display domain patterns in equilibrium. The phenomenology of these patterns, and of the shapes of their constituent domains, is reviewed here from a point of view that interprets these patterns as a manifestation of modulated phases. These phases are stabilized by competing interactions and are characterized by periodic spatial variations of the pertinent order parameter, the corresponding modulation period generally displaying a dependence on temperature and other external fields. This simple picture provides a unifying framework to account for striking and substantial similarities revealed in the prevalent "stripe" and "bubble" morphologies as well as in commonly observed, characteristic domain-shape instabilities. Several areas of particular current interest are discussed.

https://science.sciencemag.org/content/sci/267/5197/476.full.pdf

Domain shapes and patterns: the phenomenology of modulated phases.

▪ Abstract This review summarizes results for Rayleigh-Benard convection that have been obtained over the past decade or so. It concentrates on convection in compressed gases and gas mixtures with Prandtl numbers near one and smaller. In addition to the classical problem of a horizontal stationary fluid layer heated from below, it also briefly covers convection in such a layer with rotation about a vertical axis, with inclination, and with modulation of the vertical acceleration.

Recent Developments in Rayleigh-Bénard Convection

Parametric excitation of surface waves via forced vertical oscillation of a container filled with fluid (the Faraday instability) is investigated experimentally in a small-depth large-aspect-ratio system, with a viscous fluid and with two simultaneous forcing frequencies. The asymptotic pattern observed just above the threshold for the first instability of the flat surface is found to depend strongly on the frequency ratio and the amplitudes and phases of the two sinusoidal components of the driving acceleration. Parallel lines, squares, and hexagons are observed. With viscosity 100 cS, these stable standing-wave patterns do not exhibit strong sidewall effects, and are found in containers of various shapes including an irregular shape. A ‘quasi-pattern’ of twelvefold symmetry, analogous to a two-dimensional quasi-crystal, is observed for some even/odd frequency ratios. Many of the experimental phenomena can be modelled via cubic-order amplitude equations derived from symmetry arguments.

Patterns and quasi-patterns in the Faraday experiment

Patterns and spatiotemporal chaos in parametrically forced surface waves: a systematic survey at large aspect ratio

We present experimental studies of the transitions between conduction, hexagons, and rolls in non-Boussinesq convection of gaseous ${\mathrm{CO}}_{2}$ in a cylindrical cell of radius-to-height ratio 86. Except for the transition from conduction to hexagons, transitions occur when the two states involved have nearly the same value of a generalized potential rather than at the stability limits. Conduction gives way to hexagons via the propagation of a front connecting the two states, while the transitions between hexagons and rolls are facilitated at the cell walls which appear to nucleate the minority state.

J. R. De bruyn

Papers

Transitions between patterns in thermal convection.