Metal–Organic Frameworks for Separations

3.2.3. Hydroformylation 2467 3.2.4. Dimerization 2468 3.2.5. Oxidative Cleavage and Ozonolysis 2469 3.2.6. Metathesis 2470 4. Terpenes 2472 4.1. Pinene 2472 4.1.1. Isomerization: R-Pinene 2472 4.1.2. Epoxidation of R-Pinene 2475 4.1.3. Isomerization of R-Pinene Oxide 2477 4.1.4. Hydration of R-Pinene: R-Terpineol 2478 4.1.5. Dehydroisomerization 2479 4.2. Limonene 2480 4.2.1. Isomerization 2480 4.2.2. Epoxidation: Limonene Oxide 2480 4.2.3. Isomerization of Limonene Oxide 2481 4.2.4. Dehydroisomerization of Limonene and Terpenes To Produce Cymene 2481

Chemical Routes for the Transformation of Biomass into Chemicals

"Space—the final frontier." This preamble to a well-known television series captures the challenge encountered not only in space travel adventures, but also in the field of porous materials, which aims to control the size, shape and uniformity of the porous space and the atoms and molecules that define it. The past decade has seen significant advances in the ability to fabricate new porous solids with ordered structures from a wide range of different materials. This has resulted in materials with unusual properties and broadened their application range beyond the traditional use as catalysts and adsorbents. In fact, porous materials now seem set to contribute to developments in areas ranging from microelectronics to medical diagnosis.

Ordered porous materials for emerging applications

Jenny Schneider,*,† Masaya Matsuoka,‡ Masato Takeuchi,‡ Jinlong Zhang, Yu Horiuchi,‡ Masakazu Anpo,‡ and Detlef W. Bahnemann*,† †Institut fur Technische Chemie, Leibniz Universitaẗ Hannover, Callinstrasse 3, D-30167 Hannover, Germany ‡Faculty of Engineering, Osaka Prefecture University, 1 Gakuen-cho, Sakai Osaka 599-8531, Japan Key Lab for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, Shanghai 200237, China

Understanding TiO2 photocatalysis: mechanisms and materials.

4.3. Reaction Mechanism 2373 4.4. Asymmetric Synthesis 2374 4.5. Outlook 2374 5. Alternating Polymerization of Oxiranes and CO2 2374 5.1. Reaction Outlines 2374 5.2. Catalyst 2376 5.3. Asymmetric Polymerization 2377 5.4. Immobilized Catalysts 2377 6. Synthesis of Urea and Urethane Derivatives 2378 7. Synthesis of Carboxylic Acid 2379 8. Synthesis of Esters and Lactones 2380 9. Synthesis of Isocyanates 2382 10. Hydrogenation and Hydroformylation, and Alcohol Homologation 2382

Transformation of carbon dioxide.

Bench-Scale Demonstration of an Integrated deSoot-deNOx System

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Oxidation Tools in the Synthesis of Catalysts and Related Functional Materials

Publisher Summary This chapter discusses catalytic nitrous oxide (N2O) decomposition over FeZSM-5 prepared by a novel ex-framework method. This method comprises the introduction of iron (Fe) in the MFI framework, followed by calcinations and steam treatment to extract the iron to extraframework positions. The ex-framework method induces superior activity for direct N2O decomposition, compared to FeZSM-5 catalysts prepared by solid and aqueous ion-exchange methods. The extraordinary catalytic performance of ex-FeZSM-5 is attributed to the highly dispersed state of the Fe in the zeolite matrix and the Fe(III)/Fe(II) redox behavior of a significant fraction of the iron centers in the catalyst.

30-O-02-Characterization and performance of ex-framework FeZSM-5 in catalytic N2O decomposition

Estimation of kinetic parameters from non-isothermally operated monolithic reactors: Oxidation of carbon monoxide

The kinetic model developed in this work satisfactorily describes the cracking of a paraffinic feedstock starting from zero residence time.

Jacob A. Moulijn

Papers

Bench-Scale Demonstration of an Integrated deSoot-deNOx System

Oxidation Tools in the Synthesis of Catalysts and Related Functional Materials

30-O-02-Characterization and performance of ex-framework FeZSM-5 in catalytic N2O decomposition

Estimation of kinetic parameters from non-isothermally operated monolithic reactors: Oxidation of carbon monoxide

Development of a kinetic model for FCC valid from zero seconds residence time