J
James E. Galle
Researcher at Binghamton University
Publications - 36
Citations - 1000
James E. Galle is an academic researcher from Binghamton University. The author has contributed to research in topics: Group 2 organometallic chemistry & Trimethylsilyl. The author has an hindex of 17, co-authored 36 publications receiving 969 citations.
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Bora-aromatic systems. Part 8. The physical and chemical consequences of cyclic conjugation in boracyclopolyenes. The antiaromatic character of pentaarylboroles.
TL;DR: From such considerations, it is evident that the conjugation between the tricoordinate boron's 2p,-orbital and the four-carbon butadienylidene array is destabilizing and is the source of the high reactivity of boroles.
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Rearrangements of organometallic compounds. XIII. Boraaromatic systems. IV. Synthesis of heptaphenylborepin via the thermal rearrangement of heptaphenyl-7-borabicyclo[2.2.1]heptadiene
John J. Eisch,James E. Galle +1 more
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Bora-aromatic systems. 12. Thermal generation and transformation of the borepin ring system: a paradigm of pericyclic processes
TL;DR: The overall conversion of borole to this isomer of borepin involves a remarkable sequence of pericyclic reactions: a Diels-Alder cycloaddition, 1,3-sigmatropic suprafacial rearrangements of the resulting 7-borabicyclo[2.2.1]heptadiene, a 1,6-disrotatory electrocyclic ring opening to the borepin, a 3-sigmaropic ring expansion to a boracyclonononatetraene, and a final
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Organosilicon compounds with functional groups proximate to silicon. Feasible route to 1,2-epoxyalkyllithium reagents via the lithiation of epoxyethylsilanes
John J. Eisch,James E. Galle +1 more
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Functionalized organolithium reagents. 8. Novel (.alpha.,.beta.-epoxyalkyl)lithium reagents via the lithiation of organyl-substituted epoxides
John J. Eisch,James E. Galle +1 more
TL;DR: A series of epoxides bearing unsaturated organyl groups attached directly to the epoxy group was found to have sufficient kinetic acidity to undergo clean lithiation at low temperatures as mentioned in this paper.