J
Jeremy S. L. Yeo
Researcher at National University of Singapore
Publications - 11
Citations - 241
Jeremy S. L. Yeo is an academic researcher from National University of Singapore. The author has contributed to research in topics: Phosphine & Crystal structure. The author has an hindex of 10, co-authored 11 publications receiving 232 citations.
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Journal ArticleDOI
[PdCl2(dppfO2-O,O′)]: a simple palladium(II) complex with a rare tetrahedral structure
TL;DR: In this article, single-crystal X-ray diffraction analysis of PdCl2 (dppfO2) showed a rare tetrahedral geometry at a d8 metal center; physical and spectroscopic characterisations indicate a paramagnetic species.
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Exploring the Lewis basicity of the metalloligand [Pt2(μ-Se)2(PPh3)4] on metal substrates by electrospray mass spectrometry. Synthesis, characterization and structural studies of new platinum selenido phosphine complexes containing the {Pt2Se2} core
TL;DR: In this paper, a three-step strategy is employed in the use of ESMS as a probe: preliminary screening of the metalloligand with an array of acidic main group and transition group metal compounds, identification of potentially stable and isolable products in situ based on ion distribution and simulated isotope patterns and promising reactions are repeated on a laboratory scale, and target products are isolated and characterized.
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Ligand functionalization, reactivity, and transformation at the selenide centers of [Pt2(μ-Se)2(PPh3)4] with organic halides
TL;DR: In this paper, the selenium centers of [Pt2(μ-Se)2(PPh3)4] are subject to electrophilic attack from various organic halides.
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Metal scrambling in the trinuclear (Pt(2)Se(2)M)(M = Pt, Pd, Au) system using an electrospray mass spectrometry (ESMS) directed synthetic methodology; isolation and crystallographic characterization of (Pt(2)(mu(3)-Se)(2)(PPh(3))(4)[Pt(cod)])(PF(6))(2) and (Pt(mu(3)-Se)(2)(PPh(3))(2)[Pt(cod)](2))(PF(6))(2) (cod = cyclo-octa-1,5-diene).
TL;DR: In this article, the formation of these species was detected and followed by electrospray mass spectrometry (ESMS) and subsequently verified by batch synthesis and crystallographic characterization.
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Probing the Lewis basicity of the metalloligand [Pt2(μ-Se)2(PPh3)4] on tin substrates by electrospray mass spectrometry
TL;DR: In this article, the authors used ESMS to probe the reactivity of [Pt2(μ-Se)2(PPh3)4] with tin-IV substrates, which leads to the formation of charged coordination complexes via loss of halides.