The solvent-guided shaping of conjugated polymides activates O/N Zn-storage sites on the robust carbon architecture, which facilitates reversible Zn electrosorption and durable charge tansfer toward high energy-power Zn-ion capacitors. 

<i>In situ</i> nanoarchitecturing of conjugated polyamide network-derived carbon cathodes toward high energy-power Zn-ion capacitors

Challenges and design strategies for high performance aqueous zinc ion batteries

Covalent organic frameworks (COFs) are a class of porous crystalline materials whose facile preparation, functionality, and modularity have led to their becoming powerful platforms for the development of molecular devices in many fields of (bio)engineering, such as energy storage, environmental remediation, drug delivery, and catalysis. In particular, ionic COFs (iCOFs) are highly useful for constructing energy devices, as their ionic functional groups can transport ions efficiently, and the nonlabile and highly ordered all-covalent pore structures of their backbones provide ideal pathways for long-term ionic transport under harsh electrochemical conditions. Here, current research progress on the use of iCOFs for energy devices, specifically lithium-based batteries and fuel cells, is reviewed in terms of iCOF backbone-design strategies, synthetic approaches, properties, engineering techniques, and applications. iCOFs are categorized as anionic COFs or cationic COFs, and how each of these types of iCOFs transport lithium ions, protons, or hydroxides is illustrated. Finally, the current challenges to and future opportunities for the utilization of iCOFs in energy devices are described. This review will therefore serve as a useful reference on state-of-the-art iCOF design and application strategies focusing on energy devices.

Ionic Covalent Organic Frameworks for Energy Devices

All-in-one hybrid composite fiber integrates ultrahigh energy storage performance and superior mechanical stability.

https://www.science.org/doi/pdf/10.1126/sciadv.abl8631?download=true

All-in-one flexible supercapacitor with ultrastable performance under extreme load

Catalytic effect in Li-S batteries: From band theory to practical application

With the ever-increasing adaption of large-scale energy storage systems and electric devices, the energy storage capability of batteries and supercapacitors has faced increased demand and challenges. The electrodes of these devices have experienced radical change with the introduction of nano-scale materials. As new generation materials, heterostructure materials have attracted increasing attention due to their unique interfaces, robust architectures, and synergistic effects, and thus, the ability to enhance the energy/power outputs as well as the lifespan of batteries. In this review, the recent progress in heterostructure from energy storage fields is summarized. Specifically, the fundamental natures of heterostructures, including charge redistribution, built-in electric field, and associated energy storage mechanisms, are summarized and discussed in detail. Furthermore, various synthesis routes for heterostructures in energy storage fields are roundly reviewed, and their advantages and drawbacks are analyzed. The superiorities and current achievements of heterostructure materials in lithium-ion batteries (LIBs), sodium-ion batteries (SIBs), lithium-sulfur batteries (Li-S batteries), supercapacitors, and other energy storage devices are discussed. Finally, the authors conclude with the current challenges and perspectives of the heterostructure materials for the fields of energy storage.

Jiawei Zhang

Papers

Emerging of Heterostructure Materials in Energy Storage: A Review.