J
Jinbo Hu
Researcher at Chinese Academy of Sciences
Publications - 70
Citations - 2566
Jinbo Hu is an academic researcher from Chinese Academy of Sciences. The author has contributed to research in topics: Nucleophile & Sulfone. The author has an hindex of 26, co-authored 70 publications receiving 2303 citations. Previous affiliations of Jinbo Hu include University of Southern California.
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Journal ArticleDOI
The unique fluorine effects in organic reactions: recent facts and insights into fluoroalkylations
Chuanfa Ni,Jinbo Hu +1 more
TL;DR: This tutorial review provides a brief overview of the unique fluorine effects in recently developed nucleophilic, electrophilic, radical, and transition metal-mediated fluoroalkylation reactions by comparing with either their non-fluorinated counterparts or fluorinated counterparts with different numbers of fluorine substituents.
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Selective fluoroalkylations with fluorinated sulfones, sulfoxides, and sulfides.
G. K. Surya Prakash,Jinbo Hu +1 more
TL;DR: The chemistry not only provides practically powerful synthetic methods, but the molecular design concept that is developed may also be adopted to tackle other related chemical problems.
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Preparation of Tri- and Difluoromethylsilanes via an Unusual Magnesium Metal-Mediated Reductive Tri- and Difluoromethylation of Chlorosilanes Using Tri- and Difluoromethyl Sulfides, Sulfoxides, and Sulfones
TL;DR: The method can be considered to be catalytic in diphenyl disulfide for the preparation of (trifluoromethyl)trimethylsilane (TMS-CF(3)H) from non-ozone-depleting triflu oromethane.
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Nucleophilic Fluoroalkylation of α,β-Enones, Arynes, and Activated Alkynes with Fluorinated Sulfones: Probing the Hard/Soft Nature of Fluorinated Carbanions
Chuanfa Ni,Laijun Zhang,Jinbo Hu +2 more
TL;DR: It turned out that the softness of a fluorine-bearing carbanion plays a crucial role for the success of the nucleophilic fluoroalkylation reactions with arynes and some activated alkynes (alpha,beta-acetylenic ketones).
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Nucleophilic fluoroalkylation of epoxides with fluorinated sulfones.
Chuanfa Ni,Ya Li,Jinbo Hu +2 more
TL;DR: The mediation of this fluorine effect by introducing another electron-withdrawing benzenesulfonyl group was found to be an effective way to significantly increase the nucleophilicity of the fluorinated carbanions.